(a) Interpretation: The structure from the given IUPAC name is to be drawn. Concept introduction: The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group . The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Question

#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

Answer 1

Question

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

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Answer 3

Question

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

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Answer 4

Question

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

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Answer 5

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

Answer 6

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 7

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

Answer 14

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Answer 25

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The structure for the given IUPAC name is drawn by identifying the highest priority functional group from the suffix, main ring from root name and the number of substituents from locators.

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Chapter E Solutions