(a) Interpretation: The complete IUPAC name for the given compound is to be written. Concept introduction: In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

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Answer 1

Question

Chapter E, Problem E.38P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter E, Problem E.38P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

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Answer 3

Question

Chapter E, Problem E.38P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

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Answer 4

Question

Chapter E, Problem E.38P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

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Answer 5

Chapter E, Problem E.38P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 6

Chapter E, Problem E.38P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 7

Chapter E, Problem E.38P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 12

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 13

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given compound is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the “e” from the normal ane, ene, or yne ending and add the suffix that corresponds to the highest-priority functional group. If the highest priority group is present twice, then no need to remove the “e” from ane, ene, or yne ending, and prefixes are used to denote the number of identical functional groups. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains the IUPAC name for a compound by identifying the parent chain containing the functional group and substituents attached.

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