(a) Interpretation: The structure for the molecule corresponding to the given IUPAC name, is to be drawn. Concept introduction: In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group . The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of the substituents indicate the carbon atoms of the root to which they are attached.

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Answer 1

Question

Chapter E, Problem E.29P

Interpretation Introduction

(a)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name, is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of the substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(b)

Interpretation:

The structure for the molecule is to be drawn that corresponds to the given IUPAC name.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(c)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(d)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

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What are the IUPAC Names of all the compounds in the picture?

1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Answer 2

Question

Chapter E, Problem E.29P

Interpretation Introduction

(a)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name, is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of the substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(b)

Interpretation:

The structure for the molecule is to be drawn that corresponds to the given IUPAC name.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(c)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(d)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

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Answer 3

Question

Chapter E, Problem E.29P

Interpretation Introduction

(a)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name, is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of the substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(b)

Interpretation:

The structure for the molecule is to be drawn that corresponds to the given IUPAC name.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(c)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(d)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

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Answer 4

Question

Chapter E, Problem E.29P

Interpretation Introduction

(a)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name, is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of the substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(b)

Interpretation:

The structure for the molecule is to be drawn that corresponds to the given IUPAC name.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(c)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(d)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

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Answer 5

Chapter E, Problem E.29P

Interpretation Introduction

(a)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name, is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of the substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(b)

Interpretation:

The structure for the molecule is to be drawn that corresponds to the given IUPAC name.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(c)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Interpretation Introduction

(d)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Answer 6

Chapter E, Problem E.29P

Interpretation Introduction

(a)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name, is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of the substituents indicate the carbon atoms of the root to which they are attached.

Answer 7

Chapter E, Problem E.29P

Interpretation Introduction

(a)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name, is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of the substituents indicate the carbon atoms of the root to which they are attached.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure for the molecule is to be drawn that corresponds to the given IUPAC name.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure for the molecule is to be drawn that corresponds to the given IUPAC name.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure for the molecule corresponding to the given IUPAC name is to be drawn.

Concept introduction:

In the given IUPAC name, the end part of the name indicates the longest continuous carbon chain or largest ring that is established as the root. The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group. The locator numbers which are written immediately before the name of substituents indicate the carbon atoms of the root to which they are attached.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The structure for pentan-1-ol corresponds to the given IUPAC name.

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Chapter E Solutions