(a) Interpretation: The complete IUPAC name of the given molecule is to be written. Concept introduction: The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

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Answer 1

Question

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

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Answer 3

Question

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

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Answer 4

Question

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

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Answer 5

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 6

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 7

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains that the IUPAC name of a compound consists of three parts, prefix, root and suffix.

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