EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
2nd Edition
ISBN: 9780393543971
Author: KARTY
Publisher: VST
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Question
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Chapter E, Problem E.24P
Interpretation Introduction

(a)

Interpretation:

For the given alcohol, the complete IUPAC name is to be written.

Concept introduction:

In naming organic compounds, first identify the longest carbon chain or a ring containing a functional group. Name the parent chain or a ring by replacing ‘e’ from the name of parent alkyl chain by ‘ol’ for alcohol functional group. Number the carbon chain in a way that the functional group gets the lowest number.

Interpretation Introduction

(b)

Interpretation:

For the given alcohol, the complete IUPAC name is to be written.

Concept introduction:

In naming organic compounds, first identify the longest carbon chain or a ring containing functional group. Name the parent chain or a ring by replacing ‘e’ from the name of parent alkyl chain by ‘ol’ for alcohol functional group. Number the carbon chain in a way the functional group gets lowest number. Name the parent chain or a ring by replacing ‘e’ from the name of parent alkyl chain by ‘ol’ for alcohol functional group. Number the carbon chain in a way the functional group and the substituents attached gets lowest number. The position of substituents on parent chain or ring is indicated by the respective locant number.

Interpretation Introduction

(c)

Interpretation:

For the given alcohol, the complete IUPAC name is to be written.

Concept introduction:

In naming organic compounds, the functional groups other than highest priority functional groups are treated as substituents. First identify the longest carbon chain or a ring containing functional group. Name the parent chain or a ring by replacing ‘e’ from the name of parent alkyl chain by ‘ol’ for alcohol functional group. Number the carbon chain in a way the functional group gets lowest number. Name the parent chain or a ring by replacing ‘e’ from the name of parent alkyl chain by ‘ol’ for alcohol functional group. Number the carbon chain in a way the functional group and the substituents attached gets lowest number. The position of substituents on parent chain or ring is indicated by the respective locant number. Prefixes are used to denote number of identical substituents.

Interpretation Introduction

(d)

Interpretation:

For the given alcohol, the complete IUPAC name is to be written.

Concept introduction:

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."
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