(a)
Interpretation:
Amount of solute or solvent needed to prepare the following solution is to be identified.
Concept Introduction:
In order to express the concentration, many units have been used. One among them is
(b)
Interpretation:
Use of
Concept Introduction:
In order to express the concentration, many units have been used. One among them is
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FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
- The standard enthalpy of formation of ammonia at 25°C is -46.3 kJ/mol. Estimate the N-H bond enthalpy at this temperature. (Given: BE(NN) - 941.4 kJ/mol, BE(H-H) 436.4 kJ/mol) 360 kJ/mol × O 383 kJ/mol O391 kJ/mol O459 kJ/mol O475 kJ/mol Your answer is incorrect. Garrow_forwardCalculate the normality of a solution that contains 4.5 g of (COOH)2 in 3000 mL of solution? (Assume the (COOH)2 is to be completely neutralized in an acid-base * reaction.) 0.033 N O 0.33 N O 0.166 N O 0.0166 N 0.45 N O 0.045 N 000.0 OOarrow_forwardHow many grams of NaOH are needed to make 50 mL of a 0.02 g/mL NaOH solution? How many grams of HCl are needed to make 10 uL of a 0.005g/mL acid solution? How many grams of CuSO4 would you use to make 1 L of an 8 g/L CuSO4 solution? 12 grams of glucose will make how many mL of a 0.5 g/mL solution? If you mix 9 g of NaOH with 90 mL of water, what is the mass/volume (g/mL) concentration of the solution?arrow_forward
- If an aqueous solution has a hydroxyl ion concentration of 1 × 10-6 M, what is the concentration of hydrogen ion ([H+]) ? [H+] = 1.0 x10-5 Marrow_forwardQuinine ( C20 H24 N2 O2) is the most important alkaloid derived from cinchona bark. It is used as an antimalarial drug. For quinine, pK, = 5.1 and pK, = 9.7 ( pKp = – log Kp). Only 1 g quinine will dissolve in 1920.0 mL of solution. Calculate the pH of a saturated aqueous solution of quinine. Consider only the reaction | Q+ H2O= QH+ + OH- described by pK, where Q = quinine. pH =arrow_forwardTo prepare 1.00 L of a 50.0 mM NEM (N-ethyl morpholine, pKa of its conjugate acid is 7.67) buffer at pH 6.8, the amount of N-ethylmorpholine (density = 0.916 g/mL, MW = 115.17 g/mol ) needed is ______g or ______mL. Since NEM is the weak base, HCl is needed to adjust the pH to the final pH of 6.8. For this purpose, the estimated amount of a 10 M HCl needed is ______mL.arrow_forward
- 6 x 10⁻⁵¹ = (0.15 M)² [S²⁻] [S²⁻] = (6 x 10⁻⁵¹) / (0.15 M)² Calculating, we find the minimum concentration of sulfide ion required: [S²⁻] ≈ 2.7 x 10⁻⁴⁹ M. check it calcution is writearrow_forwardDescribe the preparation of 2.00 L of 0.100 M glycine buffer, pH 9.0, from glycine and 1.00 M NaOH. What mass of glycine is required, and what volume of 1.00 NaOH is required? The appropriate pKa of glycine is 9.6arrow_forward(a) Cholesterol isolated from natural sources is enantiopure. The observed rotation of a 0.3-g sample of cholesterol in 15 mL of chloroform solution contained in a 10-cm polarimeter tube is −0.78°. Calculate the specific rotation of cholesterol. (b) A sample of synthetic cholesterol consisting entirely of (+)-cholesterol was mixed with some natural (−)-cholesterol. The specific rotation of the mixture was −13°. What fraction of the mixture was (+)-cholesterol?arrow_forward
- Mixtures of amino acids can be analyzed by first separating the mixture into its components through ion‑exchange chromatography. Amino acids placed on a cation‑exchange resin containing sulfonate (−SO−3)(−SO3−) groups flow down the column at different rates because of two factors that influence their movement: (1) ionic attraction between the sulfonate residues on the column and positively charged functional groups on the amino acids, and (2) aggregation of nonpolar amino acid side chains with the hydrophobic backbone of the polystyrene resin. Note that the ionic attraction is more important than hydrophobicity for this column media. For each pair of amino acids, identify which will be eluted first from a cation‑exchange column using a pH 7.0pH 7.0 buffer.arrow_forwardUsing your stock solution of 2 M glucose, you need to prepare the following series of glucose solutions for use in an experiment 0.8; 1.5, 1.75 and 2 M. Complete the table to show how you would dilute the sucrose to make 100ml of each of the solutions above.arrow_forwardThe main constituents in vinegar are water and ethanoic acid (CH3COOH). In order to determine the concentration of acid in homemade vinegar, a student titrated 25 cm3 of 001 M NaOH against the vinegar. The equation for the reaction is: CH3COOH(aq) + NaOH(aq) ® CH3COONa(aq) + H2O(l) The following titration results were obtained: Burette readings (cm3) Rough 1 2 Final burette reading 20.10 38.90 31.40 Initial burette reading 0.10 20.00 12.50 Volume of vinegar used 20.00 18.90 18.90 (a) What volume of vinegar should be used in the calculation? (b) What is the mole ratio of NaOH:CH3COOH? (c) Calculate the number of moles of alkali in 25 cm3 of NaOH solution used. (d) How many moles of acid were used in the titration? (e) Calculate the…arrow_forward