FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
16th Edition
ISBN: 9781323406038
Author: McMurry
Publisher: PEARSON C
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Textbook Question
Chapter 9.9, Problem 9.23P
What is the freezing point of a solution of 1.0 mol of glucose in 1.0 kg of water?
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The enzyme lactate dehydrogenase (LDH) catalyzes the conversion of pyruvate to lactatein skeletal muscle cells using NAD/NADH during anaerobic “balanced” fermentation.Answer the following questions about this reaction.
(a) Write out the two reductive half reactions and indicate the E ̊' for each half reaction. Write out the full balanced reaction for the pyruvate to lactate rxn and indicate the ∆E ̊' for the reaction.
(b) What is the free energy change under standard state conditions for thisreaction? Which direction is spontaneous?(c) Assume that in skeletal muscle cells the ratio of [NAD+] to [NADH] is 100, and that the[pyruvate] = 0.40 mM and [lactate] = 4.0 mM. What is the free energy change (∆G')for the conversion of pyruvate to lactate? Indicate the direction in which the reactionis spontaneous under these cellular conditions.
Why did the authors worry about the temperature-dependent solubility of the carriers in thebilayer? How did the authors determine whether the effect of freezing the lipid bilayer wasto decrease the solubility of the carriers (nonactin and valinomycin) or whether the effectwas to impair their ability to diffuse through the membrane (decrease their mobility)?
Kranse et. al. measured the temperature dependence of conductance using membranescontaining the phospholipids glyceryl dipalmitate and glyceryl distearate. Describe themodifications in membrane content that you would employ to:
(a) shift the temperature of the phase transition
(b) make the ion conductance curve for valinomycin andnonactin more like that of gramicidin
Chapter 9 Solutions
FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
Ch. 9.1 - Classify the following liquid mixtures as...Ch. 9.2 - Write the formula of sodium sulfate decahydrate,...Ch. 9.2 - What mass of Glaubers salt must be used to provide...Ch. 9.2 - Which of the following pairs of substances would...Ch. 9.4 - A solution is prepared by dissolving 12.5 g of KBr...Ch. 9.5 - Prob. 9.4PCh. 9.5 - Prob. 9.5PCh. 9.6 - How does the body increase oxygen availability at...Ch. 9.6 - A metal alloy contains 15.8% nickel (m/m)%. What...Ch. 9.6 - Prob. 9.7P
Ch. 9.6 - Prob. 9.8PCh. 9.6 - Prob. 9.9PCh. 9.6 - Prob. 9.10PCh. 9.6 - Prob. 9.11PCh. 9.6 - What is the molarity of a solution that contains...Ch. 9.6 - How many moles of solute are present in the...Ch. 9.6 - The concentration of cholesterol (C27H46O) in...Ch. 9.6 - Prob. 9.15PCh. 9.7 - Prob. 9.16PCh. 9.7 - Prob. 9.17PCh. 9.8 - Prob. 9.5CIAPCh. 9.8 - Prob. 9.6CIAPCh. 9.8 - Prob. 9.7CIAPCh. 9.8 - Prob. 9.18PCh. 9.8 - Prob. 9.19PCh. 9.9 - A solution is prepared by dissolving 0.67 mol of...Ch. 9.9 - Prob. 9.21PCh. 9.9 - Prob. 9.22KCPCh. 9.9 - What is the freezing point of a solution of 1.0...Ch. 9.9 - Prob. 9.24PCh. 9.10 - What is the osmolarity of the following solutions?...Ch. 9.10 - Prob. 9.26PCh. 9.11 - Prob. 9.8CIAPCh. 9.11 - Prob. 9.9CIAPCh. 9 - Assume that two liquids are separated by a...Ch. 9 - Prob. 9.28UKCCh. 9 - Prob. 9.29UKCCh. 9 - Assume that you have two full beakers, one...Ch. 9 - A beaker containing 150.0 mL of 0.1 M glucose is...Ch. 9 - Prob. 9.32APCh. 9 - Prob. 9.33APCh. 9 - Prob. 9.34APCh. 9 - Prob. 9.35APCh. 9 - Which of the following are solutions? (a)Italian...Ch. 9 - Prob. 9.37APCh. 9 - The solubility of NH3 gas in water at an NH3...Ch. 9 - Prob. 9.39APCh. 9 - Is a solution highly concentrated if it is...Ch. 9 - How is mass/volume percent concentration defined...Ch. 9 - Prob. 9.42APCh. 9 - Prob. 9.43APCh. 9 - A 750.0 mL bottle of Listerine is of a 21% (v/v)...Ch. 9 - Prob. 9.45APCh. 9 - Prob. 9.46APCh. 9 - Prob. 9.47APCh. 9 - Prob. 9.48APCh. 9 - Prob. 9.49APCh. 9 - How many moles of each substance are needed to...Ch. 9 - Prob. 9.51APCh. 9 - If you had only 23 g of KOH remaining in a bottle,...Ch. 9 - Prob. 9.53APCh. 9 - The lethal dosage of potassium cyanide (KCN) in...Ch. 9 - What is the molarity of the following solutions?...Ch. 9 - How many grams of solute are in the following...Ch. 9 - How many milliliters of a 0.75 M HCl solution do...Ch. 9 - Prob. 9.58APCh. 9 - Prob. 9.59APCh. 9 - Sodium thiosulfate (Na2S2O3), the major component...Ch. 9 - Prob. 9.61APCh. 9 - What is the final volume of NaOH solution prepared...Ch. 9 - Prob. 9.63APCh. 9 - What is the concentration of a NaCl solution, in...Ch. 9 - Concentrated (12.0 M) hydrochloric acid is sold...Ch. 9 - Dilute solutions of NaHCO3 are sometimes used in...Ch. 9 - Prob. 9.67APCh. 9 - Prob. 9.68APCh. 9 - Prob. 9.69APCh. 9 - What is the total anion concentration (in mEq/L)...Ch. 9 - Kaochlor, a 10% (m/v) KCl solution, is an oral...Ch. 9 - Prob. 9.72APCh. 9 - The concentration of Cl ion in blood is...Ch. 9 - Prob. 9.74APCh. 9 - Which lowers the freezing point of 2.0 kg of water...Ch. 9 - Which solution has the higher boiling point, 0.500...Ch. 9 - Methanol, CH3OH, is sometimes used as an...Ch. 9 - Hard candy is prepared by dissolving pure sugar...Ch. 9 - Prob. 9.79APCh. 9 - Prob. 9.80APCh. 9 - Which of the following solutions has the higher...Ch. 9 - Which of the following solutions will give rise to...Ch. 9 - A pickling solution for preserving food is...Ch. 9 - Prob. 9.84APCh. 9 - Prob. 9.85CPCh. 9 - Emergency treatment of cardiac arrest victims...Ch. 9 - Nitric acid, HNO3, is available commercially at a...Ch. 9 - Prob. 9.88CPCh. 9 - A typical dosage of statin drugs for the treatment...Ch. 9 - Prob. 9.90CPCh. 9 - Prob. 9.91CPCh. 9 - Prob. 9.92CPCh. 9 - Prob. 9.93CPCh. 9 - Prob. 9.94CPCh. 9 - Prob. 9.95CPCh. 9 - Prob. 9.96GPCh. 9 - Look up the maximum concentrations set by the U.S....Ch. 9 - Look up the composition of Ringers solution used...Ch. 9 - To prevent accumulation of ice on roads and...Ch. 9 - Many carbonate minerals are insoluble in water and...Ch. 9 - Prob. 9.101GP
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