FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
16th Edition
ISBN: 9781323406038
Author: McMurry
Publisher: PEARSON C
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Chapter 9.1, Problem 9.1P
Classify the following liquid mixtures as heterogeneous or homogeneous. Further classify each homogeneous mixture as a solution or colloid.
- (a) Orange juice with pulp
- (b) Apple juice
- (c) Hand lotion
- (d) Tea
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Compare and contrast the structural features of the ion carrier valinomycin with those of achannel former like gramicidin. How does structural information help explain the mechanismby which these molecules conduct ions across membranes?
A typical integral membrane protein has a stretch (or stretches) of ~20 hydrophobic aminoacids that form an α-helix that spans the bilayer (as is found in membrane proteins such asglycophorin A and bacteriorhodopsin). Compare and contrast the molecular and structural
features of gramicidin with a membrane-spanning α-helix. Explain how gramicidin can forman ion channel when a typical membrane-spanning α-helix cannot (eg, glycophorin A).
The titration curve of alanine shows the ionization of two functional groups with pK values of 2.34 and 9.69, corresponding to
the ionization of the carboxyl and the protonated amino groups, respectively. The titration of di-, tri-, and larger oligopeptides of
alanine also shows the ionization of only two functional groups, although the experimental pK values are different. The table
summarizes the trend in pK values.
Amino acid or peptide
Ala
Ala-Ala
pKj
pk₂
2.34
9.69
3.12
8.30
Ala-Ala-Ala
3.39
8.03
Ala-(Ala)-Ala, n ≥ 4
3.42
7.94
Modify the molecules to show the oligopeptide Ala-Ala-Ala. You can modify the molecules by moving, adding,
deleting, or changing atoms, bonds, or charges.
C
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c
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H с N 0
S
Cl
H
H
| | ||
H CH3
H
CH,
H CH₂
Complete the statements about the the pK, values of the Ala-Ala-Ala oligopeptide.
The pK₁ value of 3.39 is associated with the
-COO group of Ala-Ala-Ala.
The pK2 value of 8.03 is associated with the -NH
group of Ala-Ala-Ala.
Erase
Q2 Q…
Chapter 9 Solutions
FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
Ch. 9.1 - Classify the following liquid mixtures as...Ch. 9.2 - Write the formula of sodium sulfate decahydrate,...Ch. 9.2 - What mass of Glaubers salt must be used to provide...Ch. 9.2 - Which of the following pairs of substances would...Ch. 9.4 - A solution is prepared by dissolving 12.5 g of KBr...Ch. 9.5 - Prob. 9.4PCh. 9.5 - Prob. 9.5PCh. 9.6 - How does the body increase oxygen availability at...Ch. 9.6 - A metal alloy contains 15.8% nickel (m/m)%. What...Ch. 9.6 - Prob. 9.7P
Ch. 9.6 - Prob. 9.8PCh. 9.6 - Prob. 9.9PCh. 9.6 - Prob. 9.10PCh. 9.6 - Prob. 9.11PCh. 9.6 - What is the molarity of a solution that contains...Ch. 9.6 - How many moles of solute are present in the...Ch. 9.6 - The concentration of cholesterol (C27H46O) in...Ch. 9.6 - Prob. 9.15PCh. 9.7 - Prob. 9.16PCh. 9.7 - Prob. 9.17PCh. 9.8 - Prob. 9.5CIAPCh. 9.8 - Prob. 9.6CIAPCh. 9.8 - Prob. 9.7CIAPCh. 9.8 - Prob. 9.18PCh. 9.8 - Prob. 9.19PCh. 9.9 - A solution is prepared by dissolving 0.67 mol of...Ch. 9.9 - Prob. 9.21PCh. 9.9 - Prob. 9.22KCPCh. 9.9 - What is the freezing point of a solution of 1.0...Ch. 9.9 - Prob. 9.24PCh. 9.10 - What is the osmolarity of the following solutions?...Ch. 9.10 - Prob. 9.26PCh. 9.11 - Prob. 9.8CIAPCh. 9.11 - Prob. 9.9CIAPCh. 9 - Assume that two liquids are separated by a...Ch. 9 - Prob. 9.28UKCCh. 9 - Prob. 9.29UKCCh. 9 - Assume that you have two full beakers, one...Ch. 9 - A beaker containing 150.0 mL of 0.1 M glucose is...Ch. 9 - Prob. 9.32APCh. 9 - Prob. 9.33APCh. 9 - Prob. 9.34APCh. 9 - Prob. 9.35APCh. 9 - Which of the following are solutions? (a)Italian...Ch. 9 - Prob. 9.37APCh. 9 - The solubility of NH3 gas in water at an NH3...Ch. 9 - Prob. 9.39APCh. 9 - Is a solution highly concentrated if it is...Ch. 9 - How is mass/volume percent concentration defined...Ch. 9 - Prob. 9.42APCh. 9 - Prob. 9.43APCh. 9 - A 750.0 mL bottle of Listerine is of a 21% (v/v)...Ch. 9 - Prob. 9.45APCh. 9 - Prob. 9.46APCh. 9 - Prob. 9.47APCh. 9 - Prob. 9.48APCh. 9 - Prob. 9.49APCh. 9 - How many moles of each substance are needed to...Ch. 9 - Prob. 9.51APCh. 9 - If you had only 23 g of KOH remaining in a bottle,...Ch. 9 - Prob. 9.53APCh. 9 - The lethal dosage of potassium cyanide (KCN) in...Ch. 9 - What is the molarity of the following solutions?...Ch. 9 - How many grams of solute are in the following...Ch. 9 - How many milliliters of a 0.75 M HCl solution do...Ch. 9 - Prob. 9.58APCh. 9 - Prob. 9.59APCh. 9 - Sodium thiosulfate (Na2S2O3), the major component...Ch. 9 - Prob. 9.61APCh. 9 - What is the final volume of NaOH solution prepared...Ch. 9 - Prob. 9.63APCh. 9 - What is the concentration of a NaCl solution, in...Ch. 9 - Concentrated (12.0 M) hydrochloric acid is sold...Ch. 9 - Dilute solutions of NaHCO3 are sometimes used in...Ch. 9 - Prob. 9.67APCh. 9 - Prob. 9.68APCh. 9 - Prob. 9.69APCh. 9 - What is the total anion concentration (in mEq/L)...Ch. 9 - Kaochlor, a 10% (m/v) KCl solution, is an oral...Ch. 9 - Prob. 9.72APCh. 9 - The concentration of Cl ion in blood is...Ch. 9 - Prob. 9.74APCh. 9 - Which lowers the freezing point of 2.0 kg of water...Ch. 9 - Which solution has the higher boiling point, 0.500...Ch. 9 - Methanol, CH3OH, is sometimes used as an...Ch. 9 - Hard candy is prepared by dissolving pure sugar...Ch. 9 - Prob. 9.79APCh. 9 - Prob. 9.80APCh. 9 - Which of the following solutions has the higher...Ch. 9 - Which of the following solutions will give rise to...Ch. 9 - A pickling solution for preserving food is...Ch. 9 - Prob. 9.84APCh. 9 - Prob. 9.85CPCh. 9 - Emergency treatment of cardiac arrest victims...Ch. 9 - Nitric acid, HNO3, is available commercially at a...Ch. 9 - Prob. 9.88CPCh. 9 - A typical dosage of statin drugs for the treatment...Ch. 9 - Prob. 9.90CPCh. 9 - Prob. 9.91CPCh. 9 - Prob. 9.92CPCh. 9 - Prob. 9.93CPCh. 9 - Prob. 9.94CPCh. 9 - Prob. 9.95CPCh. 9 - Prob. 9.96GPCh. 9 - Look up the maximum concentrations set by the U.S....Ch. 9 - Look up the composition of Ringers solution used...Ch. 9 - To prevent accumulation of ice on roads and...Ch. 9 - Many carbonate minerals are insoluble in water and...Ch. 9 - Prob. 9.101GP
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