Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 9.3, Problem 1PPA
Practice Problem
ATTEMPT
Use valence bond theory to describe the bonding in phosphine
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Students have asked these similar questions
What is the electron pair geometry of N in NH3?
(a) Tetrahedral
(b) Trigonal Planar
(c) Square Planar
(d) Trigonal Piramidal
Sodium azide is a shock-sensitive compound that releases N2upon physical impact. The compound is used in automobileairbags. The azide ion is N3-. (a) Draw the Lewis structure of theazide ion that minimizes formal charge (it does not form a triangle).Is it linear or bent? (b) State the hybridization of the centralN atom in the azide ion. (c) How many s bonds and how manyp bonds does the central nitrogen atom make in the azide ion?
Predict the shape, state the hybridization of the central atom, and give the ideal bond angle(s) and any expected deviations in each of the following. (Type your answer using the format sp3 for sp3. Select all that apply.)
(a) BiF,2-
shape
O octahedral
(b) AsCl4
shape
O octahedral
O seesaw
O seesaw
O square pyramidal
O tetrahedral
O square pyramidal
O tetrahedral
O trigonal pyramidal
O trigonal pyramidal
hybridization
hybridization
ideal bond angle(s)
ideal bond angle(s)
O 60°
60°
O 90°
O 90°
O 109.50
O 109.50
O 120°
O 120°
deviation from ideal angle(s)
O < 60°
deviation from ideal angle(s)
O < 60°
O < 90°
O < 90°
O < 109.5°
O < 109.50
O < 120°
O < 120°
O none
O none
Chapter 9 Solutions
Chemistry
Ch. 9.1 - Practice Problem ATTEMPT
Determine the shapes of...Ch. 9.1 - Prob. 1PPBCh. 9.1 - Prob. 1PPCCh. 9.1 - 9.1.1 What are the electron-domain geometry and...Ch. 9.1 - What are the electron-domain geometry and...Ch. 9.1 - Prob. 3CPCh. 9.1 - Prob. 4CPCh. 9.1 - Prob. 5CPCh. 9.2 - Practice Problem ATTEMPT
Ethanolamine has a...Ch. 9.2 - Practice Problem BUILD
The bond angle in is...
Ch. 9.2 - Practice ProblemCONCEPTUALIZE Which of these...Ch. 9.2 - 9.2.1 Identify the polar molecules in the...Ch. 9.2 - Identify the nonpolar molecules in the following...Ch. 9.3 - Practice ProblemATTEMPT Use valence bond theory to...Ch. 9.3 - Practice ProblemBUILD For which molecule(s) can we...Ch. 9.3 - Practice ProblemCONCEPTUALIZE Which of these...Ch. 9.3 - Which of the following atoms, in its ground state,...Ch. 9.3 - According to valence bond theory, how many bonds...Ch. 9.4 - Practice Problem ATTEMPT Use hybrid orbital theory...Ch. 9.4 - Practice ProblemBUILD Use hybrid orbital theory to...Ch. 9.4 - Prob. 1PPCCh. 9.4 - How many orbitals does a set of s p 2 hybrid...Ch. 9.4 - How many p atomic orbitals are required to...Ch. 9.5 - Practice Problem ATTEMPT
The active ingredient in...Ch. 9.5 - Practice ProblemBUILD Determine the total number...Ch. 9.5 - Practice ProblemCONCEPTUALIZE In terms of valence...Ch. 9.5 - Which of the following molecules contain one or...Ch. 9.5 - 9.5.2 From left to right, give the hybridization...Ch. 9.5 - Which of the following pairs of atomic orbitals on...Ch. 9.5 - 9.5.4 Which of the following pairs of atomic...Ch. 9.6 - Practice ProblemATTEMPT Use valence bond theory...Ch. 9.6 - Prob. 1PPBCh. 9.6 - Prob. 1PPCCh. 9.6 - Prob. 1CPCh. 9.6 - Prob. 2CPCh. 9.6 - Prob. 3CPCh. 9.6 - Prob. 4CPCh. 9.7 - Prob. 1PPACh. 9.7 - Prob. 1PPBCh. 9.7 - Prob. 1PPCCh. 9.7 - Prob. 1CPCh. 9.7 - Prob. 2CPCh. 9.7 - Prob. 3CPCh. 9.7 - Prob. 4CPCh. 9.8 - Practice ProblemATTEMPT Use a combination of...Ch. 9.8 - Practice ProblemBUILD Use a combination of valence...Ch. 9.8 - Prob. 1PPCCh. 9 - Prob. 1KSPCh. 9 - Which of the following species does not have...Ch. 9 - 9.3
Which of the following species is polar?
Ch. 9 - Which of the following species is nonpolar (a) IC1...Ch. 9 - How is the geometry of a molecule defined, and why...Ch. 9 - 9.2 Sketch the shape of a linear triatomic...Ch. 9 - How many atoms are directly bonded to the central...Ch. 9 - Discuss the basic features of the VSEPR model....Ch. 9 - In the trigonal bipyramidal arrangement, why does...Ch. 9 - 9.6 Explain why the molecule is not square...Ch. 9 - Predict the geometries of the following species...Ch. 9 - Predict the geometries of the following species: (...Ch. 9 - Predict the geometry of the following molecules...Ch. 9 - Predict the geometry of the following molecules...Ch. 9 - Predict the geometry of the following ions using...Ch. 9 - 9.12 Predict the geometries of the following ions:...Ch. 9 - Describe the geometry around each of the three...Ch. 9 - 9.14 Which of the following species are...Ch. 9 - Prob. 15QPCh. 9 - The bonds in beryllium hydride ( BeH 2 ) molecules...Ch. 9 - Determine whether (a) BrF 5 and (b) BCl 3 are...Ch. 9 - Determine whether (a) OCS and (b) XeF 4 are polar.Ch. 9 - Prob. 19QPCh. 9 - Prob. 20QPCh. 9 - Prob. 21QPCh. 9 - Use valence bond theory to explain the bonding in...Ch. 9 - Prob. 23QPCh. 9 - Prob. 24QPCh. 9 - 9.25 What is the hybridization of atomic orbitals?...Ch. 9 - Prob. 26QPCh. 9 - 9.27 What is the angle between the following two...Ch. 9 - Prob. 28QPCh. 9 - Prob. 29QPCh. 9 - Prob. 30QPCh. 9 - Prob. 31QPCh. 9 - Prob. 32QPCh. 9 - Prob. 33QPCh. 9 - Prob. 34QPCh. 9 - Which of the following pairs of atomic orbitals of...Ch. 9 - Prob. 36QPCh. 9 - 9.37 Specify which hybrid orbitals are used by...Ch. 9 - The allene molecule ( H 2 C=C=CH 2 ) is linear...Ch. 9 - Prob. 39QPCh. 9 - Prob. 40QPCh. 9 - How many pi bonds and sigma bonds are there in the...Ch. 9 - Prob. 42QPCh. 9 - Benzo(a)pyrene is a potent carcinogen found in...Ch. 9 - What is molecular orbital theory? How does it...Ch. 9 - 9.45 Define the following terms: bonding molecular...Ch. 9 - Sketch the shapes of the following molecular...Ch. 9 - Explain the significance of bond order. Can bond...Ch. 9 - Explain in molecular orbital terms the changes in...Ch. 9 - 9.49 The formation of from two atoms is an...Ch. 9 - 9.50 Draw a molecular orbital energy level diagram...Ch. 9 - Prob. 51QPCh. 9 - Prob. 52QPCh. 9 - Which of these species has a longer bond, B 2 or B...Ch. 9 - Prob. 54QPCh. 9 - 9.55 Compare the Lewis and molecular orbital...Ch. 9 - Prob. 56QPCh. 9 - Prob. 57QPCh. 9 - Prob. 58QPCh. 9 - A single bond is almost always a sigma bond, and a...Ch. 9 - Prob. 60QPCh. 9 - In Chapter 8, we saw that the resonance concept is...Ch. 9 - Prob. 62QPCh. 9 - Prob. 63QPCh. 9 - Prob. 64QPCh. 9 - Nitryl fluoride ( FNO 2 ) is very reactive...Ch. 9 - Prob. 66QPCh. 9 - Prob. 67QPCh. 9 - Which of the following species is not likely to...Ch. 9 - Prob. 69APCh. 9 - Although both carbon and silicon are in Group 4A,...Ch. 9 - Predict the geometry of sulfur dichloride ( SCl 2...Ch. 9 - Antimony pentafluoride ( sbF 5 ) reacts with XeF 4...Ch. 9 - Prob. 73APCh. 9 - Prob. 74APCh. 9 - Predict the bond angles for the following...Ch. 9 - Briefly compare the VSEPR and hybridization...Ch. 9 - 9.77 Draw Lewis structures and give the other...Ch. 9 - Prob. 78APCh. 9 - Determine whether (a) PCl 5 and (b) H 2 CO (C...Ch. 9 - Prob. 80APCh. 9 - 9.81 Which of the following molecules are linear:...Ch. 9 - Prob. 82APCh. 9 - 9.83 The molecule can exist in either of the...Ch. 9 - Cyclopropane ( C 3 H 6 ) has the shape of a...Ch. 9 - Determine whether (a) CH 2 Cl 2 and (b) XeF 4 are...Ch. 9 - 9.86 Does the following molecule have a dipole...Ch. 9 - For which molecular geometries (linear, bent,...Ch. 9 - Prob. 88APCh. 9 - 9.89 Carbon suboxide is a colorless...Ch. 9 - The following molecules ( AX 4 Y 2 ) all have an...Ch. 9 - Prob. 91APCh. 9 - Write the ground-state electron configuration for...Ch. 9 - 9.93 What is the hybridization of C and of N in...Ch. 9 - The stable allotropic form of phosphorus is P 4 ,...Ch. 9 - Prob. 95APCh. 9 - Use molecular orbital theory to explain the...Ch. 9 - Carbon dioxide has a linear geometry and is...Ch. 9 - Draw three Lewis structures for compounds with the...Ch. 9 - Prob. 99APCh. 9 - Prob. 100APCh. 9 - Prob. 101APCh. 9 - Draw the Lewis structure of ketene ( C 2 H 2 O )...Ch. 9 - Prob. 103APCh. 9 - Which of the following ions possess a dipole...Ch. 9 - Prob. 105APCh. 9 - Prob. 106APCh. 9 - The compound TCDD, or...Ch. 9 - Progesterone is a hormone responsible for female...Ch. 9 - 9.109 Carbon monoxide is a poisonous compound due...Ch. 9 - Prob. 110APCh. 9 - Prob. 111APCh. 9 - Prob. 112APCh. 9 - 9.113 The compound 1,2-dichloroethane is...Ch. 9 - Consider an N 2 molecule in its first excited...Ch. 9 - Prob. 115APCh. 9 - Prob. 1SEPPCh. 9 - Prob. 2SEPPCh. 9 - These questions are not based on a descriptive...Ch. 9 - These questions are not based on a descriptive...
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