Elementary Principles of Chemical Processes, Binder Ready Version
Elementary Principles of Chemical Processes, Binder Ready Version
4th Edition
ISBN: 9781118431221
Author: Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher: WILEY
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Chapter 9, Problem 9.72P

A bituminous coal is burned with air in a boiler furnace. The coal is fed at a rate of 40,000 kg/h and has an ultimate analysis of 76wt% C, 5% H. 8% O, negligible amounts of N ( Q ˙ ) and S, and 11% noncombustible ash (see Problem 9.58), and a higher heating value of 25,700 kJ/kg. Air enters a preheater at 30°C and 1 atm with a relative humidity of 30%, exchanges heat with the hot flue gas leaving the furnace, and enters the furnace at temperature Ta(°C). The flue gas contains 7.71 mole% CO2and 1.29 mole% CO on a dry basis, and the balance is a mixture of O2, N2, and H2O. It emerges from the furnace at 260°C and is cooled to 150°C in the preheater. Noncombustible residue {slag) leaves the furnace at 450°C and has a heat capacity of 0.97 kJ/(kg·°C).

Chapter 9, Problem 9.72P, A bituminous coal is burned with air in a boiler furnace. The coal is fed at a rate of 40,000 kg/h

  1. Prove that the air-to-fuel ratio is 16.1 standard cubic meters/kg coal and that the flue gas contains 4.6% H2O by volume.
  2. Calculate the rate of cooling required to cool the flue gas from 260°C to 150°C and the temperature to which the air is preheated. {Note: A trial-and-error calculation is required.)
  3. If 60% of the heat transferred from the furnace goes into producing saturated steam at 30 bar from liquid boiler feedwater at 50°C, at what rate (kg/h) is steam generated?

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For each set of measurements below, calculate the Grubbs statistic, G, look up the appropriate critical value of G from Table 4.6, and determine whether the Grubbs test supports discarding the first value in the list at the 95% level of confidence. a) 106.0, 165.0, 167.5, 170.5, 163.5, 170.7 (Geale -2.028; Gerit 1.822; yes, the Grubbs test supports discarding 106.0) b) 214.8, 263.0, 229.9, 236.9, 221.8, 230.8, 241.1 c) 357.0, 309.3, 304.9, 314.8, 305.8, 295.3, 284.7, 299.5 TABLE 4-6 Critical values of G for rejection of outlier Number of observations otsulsve os Tenos nagsibarito G to buboxy (95% confidence) 456 1.463 1.672 1.822 7 1.938 8 upa 2.032 9 2.110 10 2.176 - 1 12 15 20 11 2.234 2.285 2.409 2.557
#1 A irreversible isothermal gas-phase isomerization reaction is given as: AB. This reaction is conducted in a 400L batch reactor and 100 mol of A (NAD = 100 mol) is charged into this reactor. The rate of reaction is determined as a function of the conversion of reactant A and the results are given below. The temperature was constant at 500K and the total pressure was constant at 830 kPa. The entering number of moles of species A is 100 mol. Calculate the time necessary to achieve 80% conversion. 0 0.1 0.2 0.4 -TA (mol/m³.s) 0.45 0.37 0.3 0.195 0.6 0.113 0.7 0.079 0.8 0.05
#3 A irreversible isothermal liquid-phase reaction is given as: A → B is conducted in continuous flow systems. The rate of reaction is determined as a function of the conversion of reactant A and the results are given below. The temperature was constant at 500K. The entering molar flow rate of A is 0.4 mol/min. a) If this reaction is conducted in two CSTRS in series. Calculate the required reactor volume of each CSTRS if conversion X₁ = 0.4 and conversion X2 = 0.8. b) If this reaction is conducted in two PFRS in series. Calculate the required reactor volume of each PFRS if conversion X₁ = 0.4 and conversion X2 = 0.8. c) If this reaction is conducted in a PFR followed by a CSTR. Calculate the required reactor volume of PFR if conversion X₁ = 0.4 and of CSTR if conversion X2 = 0.8. X -A (mol/L.min) 0 0.1 0.2 0.4 0.6 0.7 0.8 0.45 0.37 0.3 0.195 0.113 0.079 0.05

Chapter 9 Solutions

Elementary Principles of Chemical Processes, Binder Ready Version

Ch. 9 - Prob. 9.11PCh. 9 - Prob. 9.12PCh. 9 - In the production of many microelectronic devices,...Ch. 9 - Prob. 9.14PCh. 9 - Prob. 9.15PCh. 9 - Prob. 9.16PCh. 9 - Prob. 9.17PCh. 9 - Carbon monoxide at 25°C and steam at 150°C are fed...Ch. 9 - Prob. 9.19PCh. 9 - Prob. 9.20PCh. 9 - Ethyl alcohol (ethanol) can be produced by the...Ch. 9 - Prob. 9.22PCh. 9 - Prob. 9.23PCh. 9 - Prob. 9.24PCh. 9 - Formaldehyde is produced commercially by the...Ch. 9 - Prob. 9.26PCh. 9 - Prob. 9.27PCh. 9 - Prob. 9.28PCh. 9 - Prob. 9.29PCh. 9 - A gas mixture containing 85 mole% methane and the...Ch. 9 - Ethylene oxide is produced by the catalytic...Ch. 9 - Cumene (C6H5C3H7) is produced by reacting benzene...Ch. 9 - Ethylbenzene is converted to styrene in the...Ch. 9 - Prob. 9.34PCh. 9 - Prob. 9.35PCh. 9 - Prob. 9.36PCh. 9 - Prob. 9.37PCh. 9 - Coke can be converted into CO—a fuel gas—in the...Ch. 9 - Prob. 9.39PCh. 9 - Prob. 9.40PCh. 9 - Prob. 9.41PCh. 9 - The equilibrium constant for the ethane...Ch. 9 - You are checking the performance of a reactor in...Ch. 9 - Hydrogen is produced in the steam reforming of...Ch. 9 - Prob. 9.45PCh. 9 - Five cubic meters of a 1.00-molar aqueous sulfuric...Ch. 9 - Prob. 9.47PCh. 9 - Prob. 9.48PCh. 9 - Prob. 9.49PCh. 9 - Calcium chloride is a salt used in a number of...Ch. 9 - A dilute aqueous solution of sulfuric acid at 25°C...Ch. 9 - A 2.00 mole% sulfuric acid solution is neutralized...Ch. 9 - A 12.0-molar solution of sodium hydroxide (SG =...Ch. 9 - Citric acid (C6H8O7) is used in the preparation of...Ch. 9 - Ammonia scrubbing is one of many processes for...Ch. 9 - Various uses for nitric acid are given in Problem...Ch. 9 - A natural gas is analyzed and found to consist of...Ch. 9 - Prob. 9.58PCh. 9 - A fuel gas is known to contain methane, ethane,...Ch. 9 - A fuel gas containing 85.0 mole% methane and the...Ch. 9 - A mixture of air and a fine spray of gasoline at...Ch. 9 - The heating value of a fuel oil is to be measured...Ch. 9 - Methanol vapor is burned with excess air in a...Ch. 9 - Methane at 25°C is burned in a boiler furnace with...Ch. 9 - Methane is burned completely with 40% excess air....Ch. 9 - A gaseous fuel containing methane and ethane is...Ch. 9 - A coal contains 73.0 wt% C, 4.7% H (not including...Ch. 9 - A mixture of methane, ethane, and argon at 25°C is...Ch. 9 - Prob. 9.69PCh. 9 - Prob. 9.70PCh. 9 - Prob. 9.71PCh. 9 - A bituminous coal is burned with air in a boiler...Ch. 9 - Prob. 9.73PCh. 9 - A natural gas containing 82.0 mole% CH4and the...Ch. 9 - Prob. 9.75PCh. 9 - Liquid n-pentane at 25°C is burned with 30% excess...Ch. 9 - Methane is burned with 25% excess air in a...Ch. 9 - Methane and 30% excess air are to be fed to a...Ch. 9 - Prob. 9.79PCh. 9 - In Problem 9.79, the synthesis of methanol from...Ch. 9 - Natural gas that contains methane, ethane, and...Ch. 9 - Prob. 9.82PCh. 9 - The wastewater treatment plant at the Ossabaw...

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