Substitution product of 2-chloro-methyl-3 4 hexene added to a solution of sodium acetate in acetic acid has to be given. Concept Introduction: Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product. If the leaving group in S N 1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed. An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

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Chapter 9, Problem 53P

(a)

Interpretation Introduction

Interpretation:

Substitution product of 2-chloro-methyl-3 4 hexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

(b)

Interpretation Introduction

Interpretation:

Substitution product of 3-bromo-1-methylcyclohexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

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