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Chapter 9.3, Problem 17P

(a)

Interpretation Introduction

Interpretation:

The stereoisomers that are obtained from the given SN1  reaction has to be drawn.

Concept Introduction:

  • Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.
  • If the leaving group in SN1  reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.
  • An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

(b)

Interpretation Introduction

Interpretation:

The stereoisomers that are obtained from the given SN1  reaction has to be drawn.

Concept Introduction:

  • Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.
  • If the leaving group in SN1  reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.
  • An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

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Chapter 9 Solutions

Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)

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