Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Textbook Question
Chapter 9, Problem 4RQ
What hybridization is required for central atoms exhibiting trigonal bipyramidal geometry? Octahedral geometry? Describe the bonding of PF5, SF4, SF6, and IF5, using the localized electron model.
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Chapter 9 Solutions
Chemistry
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- Best Lewis Formula and Molecular Geometry A student writes the Lewis electron-dot formula for the carbonate anion, CO32, as a Does this Lewis formula obey the octet rule? Explain. What are the formal charges on the atoms? Try describing the bonding for this formula in valence bond terms. Do you have any difficulty doing this? b Does this Lewis formula give a reasonable description of the electron structure, or is there a better one? If there is a better Lewis formula, write it down and explain why it is better. c The same student writes the following resonance description for CO2: Is there something wrong with this description? (What would you predict as the geometries of these formulas?) d Is one or the other formula a better description? Could a value for the dipole moment help you decide? e Can you write a Lewis formula that gives an even better description of CO2? Explain your answer.arrow_forwardUse Lewis structures and VSEPR theory to predict the electron-region and molecular geometries of (a) PSCl3. (b) SOF6. (c) [S2O4]2. (d) [TeF4]2. Note any differences between these geometries.arrow_forwardUsing hybridization and sigma and pi bonding, explain the bonding in (a) HCN and (b) H2CNH.arrow_forward
- Draw the molecular shapes and predict the bond angles (relative to the ideal angles) of (a) SbF5 and (b) BrF5.arrow_forwardWrite the best Lewis dot structure for N₃⁻, give the electronic geometry, molecular geometry, hybridization of the central element, polarity, and bond angle around the central element.arrow_forwardWrite the best Lewis dot structure for POCl₃, be sure to give the electronic geometry, molecular geometry, hybridization of the central element, polarity, and bond angle around the central element.arrow_forward
- Do the Lewis structure of Urea (NH2)2CO 1. lewis structure2. assign the VSEPR model of the central atom3. Value of the corresponding theoretical angle4. classify 3 of the different bonds around the central atom as ionic or covalent5. draw the complete 3-D structure with respect to the central atom (s)6. draw the lewis structure for another mnolecule or species with a different atomic arrangementarrow_forwardWhat is the hybridization of the central atom in the Lewis structure for BrCl5? Is BrCl5 polar or nonpolar?arrow_forward19. What are the ideal VSEPR (electronic) and molecular geometries for SF5−−? The ideal (electronic) geometry is: T-shaped square pyramidal trigonal bipyramidal tetrahedral octahedral trigonal planar The molecular geometry is: trigonal planar square pyramidal tetrahedral trigonal bipyramidal T-shaped octahedralarrow_forward
- Give the electron geometry (eg), molecular geometry (mg), and hybridization for Cl 3. eg = tetrahedral; mg = trigonal pyramidal; sp3 eg = trigonal planar; mg = trigonal planar; sp2 eg = octahedral; mg = tetrahedral, sp3 eg = tetrahedral; mg = linear; sp3 O eg trigonal pyramidal; mg = linear; sp3arrow_forwardwhat are the bond angles of AsF4Br relative to AsF5? and why? how do the molecule structures differ?arrow_forwardwhat's the molecular shape of SF4? trigonal planar seesaw trigonal pyramidal O tetrahedralarrow_forward
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