Major and minor product should be predicted for the given alkyl halide during E1 elimination process. Concept introduction: Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2. E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation. E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state. Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat. Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

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Answer 1

Question

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Answer 2

Question

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

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Answer 3

Question

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

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Answer 4

Question

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

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Answer 5

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 6

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 7

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 8.3 - Prob. 1LTS Ch. 8.3 - Prob. 1PTS Ch. 8.3 - Prob. 2ATS Ch. 8.3 - Prob. 3ATS Ch. 8.3 - Prob. 4CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 5PTS Ch. 8.4 - Prob. 6ATS Ch. 8.5 - Prob. 3LTS Ch. 8.5 - Prob. 7PTS

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