Mechanism patterns should be compared for the given E1 elimination reactions. Concept introduction: Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another. Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc. Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. E1 elimination process: E1 process follows step-wise mechanism. Elimination of compound in presence of bulky base leads to less substituted alkene , in presence of strong base (not bulky) leads to more substituted alkene. Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Question

Want to see the full answer?

Answer 1

Question

Chapter 8.10, Problem 35ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(b)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(c)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(d)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

PROBLEMS Q1) Label the following salts as either acidic, basic, or neutral a) Fe(NOx) c) AlBr b) NH.CH COO d) HCOON (1/2 mark each) e) Fes f) NaBr Q2) What is the pH of a 0.0750 M solution of sulphuric acid?

8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major contributor in each case, or if they are equivalent (45) (2) -PH2 سمة مد

A J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3

Answer 2

Question

Chapter 8.10, Problem 35ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(b)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(c)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(d)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 8.10, Problem 35ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(b)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(c)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(d)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 8.10, Problem 35ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(b)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(c)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(d)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 8.10, Problem 35ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(b)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(c)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

(d)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Answer 6

Chapter 8.10, Problem 35ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Answer 7

Chapter 8.10, Problem 35ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Mechanism patterns should be compared for the given E1 elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

E1 elimination process: E1 process follows step-wise mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Dehydration and dehydro halogenation process takes place in presence of acid then gentle heat applied to the substrate.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 17

Ch. 8.3 - Prob. 1LTS Ch. 8.3 - Prob. 1PTS Ch. 8.3 - Prob. 2ATS Ch. 8.3 - Prob. 3ATS Ch. 8.3 - Prob. 4CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 5PTS Ch. 8.4 - Prob. 6ATS Ch. 8.5 - Prob. 3LTS Ch. 8.5 - Prob. 7PTS

Want to see the full answer?

Chapter 8 Solutions