Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions. Concept introduction: Stereo center: carbon atom with four different groups is called stereo center in organic molecules. Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement. Enantiomers: isomers are non-superimposable mirror images. Diastereomers: isomers are non-superimposable and not mirror images.

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Answer 1

Question

Chapter 8, Problem 87IP

(a)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(b)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(c)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(d)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(e)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

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8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major contributor in each case, or if they are equivalent (45) (2) -PH2 سمة مد

A J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3

1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.

Answer 2

Question

Chapter 8, Problem 87IP

(a)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(b)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(c)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(d)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(e)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

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Answer 3

Question

Chapter 8, Problem 87IP

(a)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(b)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(c)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(d)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(e)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Expert Solution & Answer

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Answer 4

Question

Chapter 8, Problem 87IP

(a)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(b)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(c)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(d)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(e)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 8, Problem 87IP

(a)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(b)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(c)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(d)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

(e)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 6

Chapter 8, Problem 87IP

(a)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 7

Chapter 8, Problem 87IP

(a)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Stereoisomers and the functional groups present in the structure pladienolide B should be predicted as per given questions.

Concept introduction:

Stereo center: carbon atom with four different groups is called stereo center in organic molecules.

Stereo isomers: stereoisomers are isomers, which are having same molecular formula but differ in their spatial arrangement.

Enantiomers: isomers are non-superimposable mirror images.

Diastereomers: isomers are non-superimposable and not mirror images.

Answer 16

Expert Solution & Answer

Answer 17

Expert Solution & Answer

Answer 18

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Answer 19

Ch. 8.3 - Prob. 1LTS Ch. 8.3 - Prob. 1PTS Ch. 8.3 - Prob. 2ATS Ch. 8.3 - Prob. 3ATS Ch. 8.3 - Prob. 4CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 5PTS Ch. 8.4 - Prob. 6ATS Ch. 8.5 - Prob. 3LTS Ch. 8.5 - Prob. 7PTS

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Chapter 8 Solutions