Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction. Concept introduction: Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2. E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration. r ∝ [substrate] E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration. r ∝ [substrate] [ base ] Elimination of compound in presence of bulky base leads to less substituted alkene , in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 1

Question

Chapter 8.7, Problem 13CC

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Answer 2

Question

Chapter 8.7, Problem 13CC

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 3

Question

Chapter 8.7, Problem 13CC

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 4

Question

Chapter 8.7, Problem 13CC

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Expert Solution & Answer

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Answer 5

Chapter 8.7, Problem 13CC

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 6

Chapter 8.7, Problem 13CC

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 7

Chapter 8.7, Problem 13CC

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 8.3 - Prob. 1LTS Ch. 8.3 - Prob. 1PTS Ch. 8.3 - Prob. 2ATS Ch. 8.3 - Prob. 3ATS Ch. 8.3 - Prob. 4CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 5PTS Ch. 8.4 - Prob. 6ATS Ch. 8.5 - Prob. 3LTS Ch. 8.5 - Prob. 7PTS

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