ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
2nd Edition
ISBN: 9781118872925
Author: Klein
Publisher: JOHN WILEY+SONS INC.CUSTOM
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Question
Chapter 8, Problem 81IP
Interpretation Introduction
Interpretation:
Mechanism should be drawn for the given elimination reactions.
Concept introduction:
- Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.
- Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.
- Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.
- Elimination of compound in presence of bulky base leads to less substituted
alkene , in presence of strong base (not bulky) leads to more substituted alkene.
Expert Solution & Answer
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NH (aq)+CNO (aq) → CO(NH2)2(s)
Experiment
[NH4] (M) [CNO] (M) Initial rate (M/s)
1
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2CIO2 + 20H-1 CIO31 + CIO2 + H2O
Experiment
[CIO2], M
[OH-1], M
1
0.0500
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23
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0.100
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0.230
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.(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I
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[1-] M
0.005
[OCI-]
0.005
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0.000275
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0.000138
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0.000069
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Chapter 8 Solutions
ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
Ch. 8.3 - Prob. 1LTSCh. 8.3 - Prob. 1PTSCh. 8.3 - Prob. 2ATSCh. 8.3 - Prob. 3ATSCh. 8.3 - Prob. 4CCCh. 8.4 - Prob. 2LTSCh. 8.4 - Prob. 5PTSCh. 8.4 - Prob. 6ATSCh. 8.5 - Prob. 3LTSCh. 8.5 - Prob. 7PTS
Ch. 8.5 - Prob. 8PTSCh. 8.6 - Prob. 4LTSCh. 8.6 - Prob. 9PTSCh. 8.6 - Prob. 10PTSCh. 8.6 - Prob. 11ATSCh. 8.6 - Prob. 12ATSCh. 8.7 - Prob. 13CCCh. 8.7 - Prob. 14CCCh. 8.7 - Prob. 5LTSCh. 8.7 - Prob. 15PTSCh. 8.7 - Prob. 16ATSCh. 8.7 - Prob. 17ATSCh. 8.7 - Prob. 6LTSCh. 8.7 - Prob. 18PTSCh. 8.7 - Prob. 19ATSCh. 8.7 - Prob. 20CCCh. 8.7 - Prob. 21CCCh. 8.8 - Prob. 7LTSCh. 8.8 - Prob. 22PTSCh. 8.8 - Prob. 23ATSCh. 8.8 - Prob. 24ATSCh. 8.8 - Prob. 25ATSCh. 8.9 - Prob. 26CCCh. 8.9 - Prob. 27CCCh. 8.9 - Prob. 28CCCh. 8.9 - Prob. 8LTSCh. 8.9 - Prob. 29PTSCh. 8.9 - Prob. 31CCCh. 8.10 - Prob. 32CCCh. 8.10 - Prob. 33CCCh. 8.10 - Prob. 9LTSCh. 8.10 - Prob. 34PTSCh. 8.10 - Prob. 35ATSCh. 8.10 - Prob. 36ATSCh. 8.11 - Prob. 37CCCh. 8.11 - Prob. 38CCCh. 8.12 - Prob. 10LTSCh. 8.13 - Prob. 11LTSCh. 8.14 - Prob. 12LTSCh. 8.14 - Prob. 46PTSCh. 8.14 - Prob. 48ATSCh. 8.14 - Prob. 49ATSCh. 8 - Prob. 50PPCh. 8 - Prob. 51PPCh. 8 - Prob. 52PPCh. 8 - Prob. 53PPCh. 8 - Prob. 54PPCh. 8 - Prob. 55PPCh. 8 - Prob. 56PPCh. 8 - Prob. 57PPCh. 8 - Prob. 58PPCh. 8 - Prob. 59PPCh. 8 - Prob. 60PPCh. 8 - Prob. 61PPCh. 8 - Prob. 62PPCh. 8 - Prob. 63PPCh. 8 - Prob. 64PPCh. 8 - Prob. 65PPCh. 8 - Prob. 66PPCh. 8 - Prob. 67PPCh. 8 - Prob. 68PPCh. 8 - Prob. 69PPCh. 8 - Prob. 70PPCh. 8 - Prob. 71PPCh. 8 - Prob. 72PPCh. 8 - Prob. 73PPCh. 8 - Prob. 74PPCh. 8 - Prob. 75PPCh. 8 - Prob. 76PPCh. 8 - Prob. 77IPCh. 8 - Prob. 78IPCh. 8 - Prob. 79IPCh. 8 - Prob. 80IPCh. 8 - Prob. 81IPCh. 8 - Prob. 82IPCh. 8 - Prob. 83IPCh. 8 - Prob. 84IPCh. 8 - Prob. 85IPCh. 8 - Prob. 86IPCh. 8 - Prob. 87IP
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