Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Textbook Question
Chapter 8, Problem 8.98PAE
8.98 If you know the density of material and the length of the edge of its cubic Iattice, how would you determine if it is face-centered cubic, body-centered cubic, or simple cubic Would you have to look up any information?
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Describe the features of the body-centered cubic unit cell?
2) Sodium is a bright and white, soft, wax-like element dissolved in seawater, crystallized in rock
salt. Sodium is common in nature and crystallizes with a body-centered cubic unit cell and its
density is 0.971 g/cm³. (Na: 23 g/mol)
(a) What is the volume of the unit cell, in cm³?
(b) What is the edge length of the unit cell, in pm?
(c) What is the radius of a sodium atom, in pm?
5. Below are listed the atomic weight, density, and atomic radius for three hypothetical elements.
For each determine whether its crystal structure is face-centered cubic (FCC), body-centered cubic
(BCC) or simple cubic (SC) and then justify your determination.
Elements
Atomic Weight (g/mol)
Density (g/cm')
Atomic Radius (nm)
A
107.6
13.42
0.133
77.4
8.22
0.125
50,9
5,96
0,132
Chapter 8 Solutions
Chemistry for Engineering Students
Ch. 8 - Prob. 1COCh. 8 - • describe the arrangement of atoms in the common...Ch. 8 - • use bind theory to describe bonding in solids.Ch. 8 - Prob. 4COCh. 8 - Prob. 5COCh. 8 - Prob. 6COCh. 8 - Prob. 7COCh. 8 - • explain the connection between intermolecular...Ch. 8 - Prob. 9COCh. 8 - Prob. 10CO
Ch. 8 - Prob. 8.1PAECh. 8 - Why is the C 60form of carbon called...Ch. 8 - Prob. 8.3PAECh. 8 - Prob. 8.4PAECh. 8 - What is the relationship between the structures of...Ch. 8 - Use the web to look up information on nanotubes....Ch. 8 - Prob. 8.7PAECh. 8 - Prob. 8.8PAECh. 8 - Prob. 8.9PAECh. 8 - Using circles, draw regular two-dimensional...Ch. 8 - Prob. 8.11PAECh. 8 - Prob. 8.12PAECh. 8 - Prob. 8.13PAECh. 8 - Prob. 8.14PAECh. 8 - 8.13 What is the coordination number of atoms in...Ch. 8 - Prob. 8.16PAECh. 8 - Prob. 8.17PAECh. 8 - 8.16 Iridium forms a face-centered cubic lattice,...Ch. 8 - 8.17 Europium forms a body-centered cubic unit...Ch. 8 - 8.18 Manganese has a body-centered cubic unit cell...Ch. 8 - Prob. 8.21PAECh. 8 - 8.20 How many electrons per atom are delocalized...Ch. 8 - Prob. 8.23PAECh. 8 - Prob. 8.24PAECh. 8 - Prob. 8.25PAECh. 8 - 8.24 What is the key difference between metallic...Ch. 8 - Prob. 8.27PAECh. 8 - Prob. 8.28PAECh. 8 - 8.25 Draw a depiction of the band structure of a...Ch. 8 - Prob. 8.30PAECh. 8 - Prob. 8.31PAECh. 8 - Prob. 8.32PAECh. 8 - Prob. 8.33PAECh. 8 - Prob. 8.34PAECh. 8 - Prob. 8.35PAECh. 8 - Prob. 8.36PAECh. 8 - Prob. 8.37PAECh. 8 - Suppose that a device is using a 15.0-mg sample of...Ch. 8 - 8.35 What is an instantancous dipole?Ch. 8 - 8.36 Why are dispersion forces attractive?Ch. 8 - 8.37 If a molecule is not very polarizable, how...Ch. 8 - 8.38 What is the relationship between...Ch. 8 - Prob. 8.43PAECh. 8 - Prob. 8.44PAECh. 8 - 8.39 Under what circumstances are ion-dipole...Ch. 8 - 8.40 Which of the following compounds would be...Ch. 8 - 8.41 What is the specific feature of N, O, and F...Ch. 8 - Prob. 8.48PAECh. 8 - 8.43 Identify the kinds of intermolecular forces...Ch. 8 - Prob. 8.50PAECh. 8 - Prob. 8.51PAECh. 8 - Explain from a molecular perspective why graphite...Ch. 8 - 8.45 Describe how interactions between molecules...Ch. 8 - 8.46 What makes a chemical compound volatile?Ch. 8 - 8.47 Answer each of the following questions with...Ch. 8 - 8.48 Why must the vapor pressure of a substance be...Ch. 8 - Prob. 8.57PAECh. 8 - Prob. 8.58PAECh. 8 - Prob. 8.59PAECh. 8 - Suppose that three unknown pure substances are...Ch. 8 - 8.51 Suppose that three unknown pure substances...Ch. 8 - 8.52 Rank the following hydrocarbons in order of...Ch. 8 - Prob. 8.63PAECh. 8 - Prob. 8.64PAECh. 8 - Prob. 8.65PAECh. 8 - Prob. 8.66PAECh. 8 - Prob. 8.67PAECh. 8 - Prob. 8.68PAECh. 8 - Why is there no isotactic or syndiotactic form of...Ch. 8 - Prob. 8.70PAECh. 8 - Prob. 8.71PAECh. 8 - Prob. 8.72PAECh. 8 - 8.61 Distinguish between a block copolymer and a...Ch. 8 - Prob. 8.74PAECh. 8 - Prob. 8.75PAECh. 8 - Prob. 8.76PAECh. 8 - Prob. 8.77PAECh. 8 - 8.66 What structural characteristics are needed...Ch. 8 - Prob. 8.79PAECh. 8 - Prob. 8.80PAECh. 8 - Prob. 8.81PAECh. 8 - Prob. 8.82PAECh. 8 - Prob. 8.83PAECh. 8 - Prob. 8.84PAECh. 8 - Prob. 8.85PAECh. 8 - Prob. 8.86PAECh. 8 - 8.87 Use the vapor pressure curves illustrated...Ch. 8 - Prob. 8.88PAECh. 8 - 8.89 The following data show the vapor pressure of...Ch. 8 - Prob. 8.90PAECh. 8 - Prob. 8.91PAECh. 8 - Prob. 8.92PAECh. 8 - Prob. 8.93PAECh. 8 - Prob. 8.94PAECh. 8 - Prob. 8.95PAECh. 8 - 8.96 A business manager wants to provide a wider...Ch. 8 - 8.97 The doping of semiconductors can be done with...Ch. 8 - 8.98 If you know the density of material and the...Ch. 8 - Prob. 8.99PAECh. 8 - Prob. 8.100PAECh. 8 - Prob. 8.101PAECh. 8 - Prob. 8.102PAECh. 8 - 8.103 In previous chapters, we have noted that...Ch. 8 - Prob. 8.104PAECh. 8 - Prob. 8.105PAE
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Metallic barium has a body-centered cubic structure (all atoms at the lattice points) and a density of 3.51 g/cm3. Assume barium atoms to be spheres. The spheres in a body-centered array occupy 68.0% of the total space. Find the atomic radius of barium. (See Problem 11.93.)arrow_forwardWhat is the coordination number of a chromium atom in the body-centered cubic structure of chromium?arrow_forwardThe ionic compound, CsI, forms a body centered cubic structure (see below) where the anions occupy the corners of the crystal (red) and the cations the body centered position (green). If the density of the compound is 4.51 g/cm^3 and the ionic radius of Cs + is 169 pm, what is the ionic radius of I − in pm? Key Concept: The atoms are touching the diagonal in the center of the cube. This makes it equal to the sum of 2 times the radius of each atom. Strategy: Determine the length of the diagonal,d, and recall that the length of the side, l, is given by l = d/3 0.5. This is a result of the use of the Pythagorean theorem relating the length of the side to d.With the length of the side you can determine the volume of the unit cell.From the number of atoms in the unit cell determine the mass of the unit cell.Use these to get the density.arrow_forward
- A hypothetical element, Le, has a body centered cubic structure with a density of 6.57 g/cm3. Calculate its atomic radius in pm. Atomic Mass: Le: 55.334 g/mol Round your answer to 2 decimal places. Add your answerarrow_forwardPlatinum nanoparticles of diameter ∼2 nm are important catalysts in carbon monoxide oxidation to carbon dioxide. Platinum crystallizes in a face-centered cubic arrangement with an edge length of 3.924 Å. (a) Estimate how many platinum atoms would fit into a 2.0-nm sphere; the volume of a sphere is 14>32pr3. Recall that 1 A ° = 1 * 10-10 m and 1 nm = 1 * 10-9 m.arrow_forwardThe ionic compound, CsCl, forms a body centered cubic structure (see below) where the anions occupy the corners of the crystal (red) and the cations the body centered position (green). If the density of the compound is 3.99 g/cm3 and the ionic radius of Cs+ is 169 pm, what is the ionic radius of Cl− in pm?arrow_forward
- In crystalline structures, there are mainly these types of structures: simple cubic, body-centered cubic, face-centered cubic, cubic close pack, hexagonal close pack. What are the types of holes associated with each one of them? Is there a quick way to memorize them?arrow_forwardThe lattice structure of CsCl is shown below. What type of a structure is this by only considering the cations present in the Figure below? simple cubic moniclinic face centered cubic body centered cubic triclinicarrow_forwardMake a drawing of each unit cell: simple cubic, body-centered cubic, and face-centered cubic.arrow_forward
- sdaswTantalum is a rare, hard, blue-gray, lustrous transition metal that is highly corrosion-resistant. It has a density of 16.1 grams per cubic centimeter and a molecular weight of 215.19 g/mol. What is the atomic radius of Ta if it adopts the body centered cubic unit structure? Express answer in scientific notation (e.g. 3.47e-23).arrow_forwardA hypothetical element, Le, has a body centered cubic structure with a density of 6.57 g/cm. Calculate its atornic radius in pm. Atomic Mass5A Le: 55.334 g/mol Round your answer to 2 decimal places.arrow_forwardA hypothetical element, Ny, forms a face-centered cubic lattice with an atomic radius of 165 pm. Calculate the density of the element in g/cm3. Atomic Mass: Ny: 112.024 g/mol Round to 2 decimal places.arrow_forward
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