Chemistry for Engineering Students
Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 8, Problem 8.92PAE
Interpretation Introduction

Interpretation:The intermolecular forces present in the spilled oil from a pipeline and the pipeline oil have to explain.

Concept Introduction:In molecules having no permanent dipole like hydrocarbons the electronic atmosphere is supposed to be symmetrical. But this is true only on a time average. Rapid and continuous changes in the intensities of charge concentration in the electron atmosphere may give rise to instantaneous and fluctuating dipoles as shown in the figure. These dipoles may induce further dipoles on adjacent molecules. The resulting weak short range forces are called London Dispersion Forces. The forces increase with increasing polarisibility and hence molar volume among comparable species. Usually these are related to molecular weight but the polarisibility is always important in this force of attraction.

Chemistry for Engineering Students, Chapter 8, Problem 8.92PAE

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Shown below are interactions that occur between ions and polar compounds (cyclopentyl alcohol, dimethyl ether, dimethyl sulfide, and water). Examine the types of intermolecular forces in which each of the following molecules participate, then rank the following interactions between molecules and ions from the weakest to the strongest based on those intermolecular forces and trends in electronegativity.
Explain each of these properties of water, and describe how each is conferred by the dipolar nature of a water molecule: high specific heat capacity; high heat of vaporization; unique density behavior; high surface tension; capacity to be a good solvent for ions of salts.
The OH covalent bond has a very high bond energy of about 463 kJ / mol. The electrostatic bond of the hydrogen bond has an energy between 10 and 40 kJ / mol. Although the hydrogen bond is relatively weak compared to the covalent bonds, it is stronger than the Van der Waals interactions and plays among other things a primordial role in the biological systems and on the physicochemical properties of water. (as heard in the 1st audio) Thus the consequences of the existence of strong hydrogen bonds are remarkable on the temperatures of change of state of water compared to compounds of similar structure. According to the following graph, 2- What are these values for water? What is the temperature range of existence of liquid water at normal pressure (1 atm)? What would these values be if the water molecule were not also polar (Extrapolate by following the dotted lines)? 100 °C 60 boiling point H2O 20 -20 H2Se H2S H,Te -60 freezing point -80 40 80 g/moi 160 masse molaire température

Chapter 8 Solutions

Chemistry for Engineering Students

Ch. 8 - Prob. 8.1PAECh. 8 - Why is the C 60form of carbon called...Ch. 8 - Prob. 8.3PAECh. 8 - Prob. 8.4PAECh. 8 - What is the relationship between the structures of...Ch. 8 - Use the web to look up information on nanotubes....Ch. 8 - Prob. 8.7PAECh. 8 - Prob. 8.8PAECh. 8 - Prob. 8.9PAECh. 8 - Using circles, draw regular two-dimensional...Ch. 8 - Prob. 8.11PAECh. 8 - Prob. 8.12PAECh. 8 - Prob. 8.13PAECh. 8 - Prob. 8.14PAECh. 8 - 8.13 What is the coordination number of atoms in...Ch. 8 - Prob. 8.16PAECh. 8 - Prob. 8.17PAECh. 8 - 8.16 Iridium forms a face-centered cubic lattice,...Ch. 8 - 8.17 Europium forms a body-centered cubic unit...Ch. 8 - 8.18 Manganese has a body-centered cubic unit cell...Ch. 8 - Prob. 8.21PAECh. 8 - 8.20 How many electrons per atom are delocalized...Ch. 8 - Prob. 8.23PAECh. 8 - Prob. 8.24PAECh. 8 - Prob. 8.25PAECh. 8 - 8.24 What is the key difference between metallic...Ch. 8 - Prob. 8.27PAECh. 8 - Prob. 8.28PAECh. 8 - 8.25 Draw a depiction of the band structure of a...Ch. 8 - Prob. 8.30PAECh. 8 - Prob. 8.31PAECh. 8 - Prob. 8.32PAECh. 8 - Prob. 8.33PAECh. 8 - Prob. 8.34PAECh. 8 - Prob. 8.35PAECh. 8 - Prob. 8.36PAECh. 8 - Prob. 8.37PAECh. 8 - Suppose that a device is using a 15.0-mg sample of...Ch. 8 - 8.35 What is an instantancous dipole?Ch. 8 - 8.36 Why are dispersion forces attractive?Ch. 8 - 8.37 If a molecule is not very polarizable, how...Ch. 8 - 8.38 What is the relationship between...Ch. 8 - Prob. 8.43PAECh. 8 - Prob. 8.44PAECh. 8 - 8.39 Under what circumstances are ion-dipole...Ch. 8 - 8.40 Which of the following compounds would be...Ch. 8 - 8.41 What is the specific feature of N, O, and F...Ch. 8 - Prob. 8.48PAECh. 8 - 8.43 Identify the kinds of intermolecular forces...Ch. 8 - Prob. 8.50PAECh. 8 - Prob. 8.51PAECh. 8 - Explain from a molecular perspective why graphite...Ch. 8 - 8.45 Describe how interactions between molecules...Ch. 8 - 8.46 What makes a chemical compound volatile?Ch. 8 - 8.47 Answer each of the following questions with...Ch. 8 - 8.48 Why must the vapor pressure of a substance be...Ch. 8 - Prob. 8.57PAECh. 8 - Prob. 8.58PAECh. 8 - Prob. 8.59PAECh. 8 - Suppose that three unknown pure substances are...Ch. 8 - 8.51 Suppose that three unknown pure substances...Ch. 8 - 8.52 Rank the following hydrocarbons in order of...Ch. 8 - Prob. 8.63PAECh. 8 - Prob. 8.64PAECh. 8 - Prob. 8.65PAECh. 8 - Prob. 8.66PAECh. 8 - Prob. 8.67PAECh. 8 - Prob. 8.68PAECh. 8 - Why is there no isotactic or syndiotactic form of...Ch. 8 - Prob. 8.70PAECh. 8 - Prob. 8.71PAECh. 8 - Prob. 8.72PAECh. 8 - 8.61 Distinguish between a block copolymer and a...Ch. 8 - Prob. 8.74PAECh. 8 - Prob. 8.75PAECh. 8 - Prob. 8.76PAECh. 8 - Prob. 8.77PAECh. 8 - 8.66 What structural characteristics are needed...Ch. 8 - Prob. 8.79PAECh. 8 - Prob. 8.80PAECh. 8 - Prob. 8.81PAECh. 8 - Prob. 8.82PAECh. 8 - Prob. 8.83PAECh. 8 - Prob. 8.84PAECh. 8 - Prob. 8.85PAECh. 8 - Prob. 8.86PAECh. 8 - 8.87 Use the vapor pressure curves illustrated...Ch. 8 - Prob. 8.88PAECh. 8 - 8.89 The following data show the vapor pressure of...Ch. 8 - Prob. 8.90PAECh. 8 - Prob. 8.91PAECh. 8 - Prob. 8.92PAECh. 8 - Prob. 8.93PAECh. 8 - Prob. 8.94PAECh. 8 - Prob. 8.95PAECh. 8 - 8.96 A business manager wants to provide a wider...Ch. 8 - 8.97 The doping of semiconductors can be done with...Ch. 8 - 8.98 If you know the density of material and the...Ch. 8 - Prob. 8.99PAECh. 8 - Prob. 8.100PAECh. 8 - Prob. 8.101PAECh. 8 - Prob. 8.102PAECh. 8 - 8.103 In previous chapters, we have noted that...Ch. 8 - Prob. 8.104PAECh. 8 - Prob. 8.105PAE
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Types of bonds; Author: Edspira;https://www.youtube.com/watch?v=Jj0V01Arebk;License: Standard YouTube License, CC-BY