General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 8, Problem 8.37SP
What is internal energy?
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 8 Solutions
General Chemistry: Atoms First
Ch. 8.2 - Which of the following are state functions, and...Ch. 8.3 - Calculate the work in kilojoules done during a...Ch. 8.3 - How much work is done in kilojoules, and in which...Ch. 8.4 - The following reaction has E = 186 kJ/mol. (a) Is...Ch. 8.5 - Assuming that Coca Cola has the same specific heat...Ch. 8.5 - What is the specific heat of lead if it takes 97.2...Ch. 8.5 - When 25.0 mL of 1.0 M H2SO4 is added to 50.0 mL of...Ch. 8.6 - The reaction between hydrogen and oxygen to yield...Ch. 8.6 - The explosion of 2.00 mol of solid trinitrotoluene...Ch. 8.7 - How much heat in kilojoules is evolved or absorbed...
Ch. 8.7 - Nitromethane (CH3NO2), sometimes used as a fuel in...Ch. 8.8 - The industrial degreasing solvent methylene...Ch. 8.8 - The reaction of A with B to give D proceeds in two...Ch. 8.8 - Draw a Hesss law diagram similar to that in...Ch. 8.9 - Use the information in Table 8.2 to calculate H in...Ch. 8.9 - Use the information in Table 8.2 to calculate H in...Ch. 8.10 - Use the data in Table 8.3 to calculate an...Ch. 8.10 - Use the data in Table 8.3 to calculate an...Ch. 8.11 - Liquid butane (C4H10), the fuel used in many...Ch. 8.12 - Ethane, C2H6, can be prepared by the reaction of...Ch. 8.12 - Is the reaction represented in the following...Ch. 8.12 - Which of the following reactions are spontaneous...Ch. 8.12 - Is the Haber process for the industrial synthesis...Ch. 8.12 - The following reaction is exothermic: (a) Write a...Ch. 8.12 - Write balanced equations for the combustion...Ch. 8.12 - Biodiesel has a more favorable (more negative)...Ch. 8 - The following reaction is exothermic: (a) Write a...Ch. 8 - Imagine a reaction that results in a change in...Ch. 8 - Redraw the following diagram to represent the...Ch. 8 - Prob. 8.30CPCh. 8 - Prob. 8.31CPCh. 8 - A reaction is carried out in a cylinder fitted...Ch. 8 - The following drawing portrays a reaction of the...Ch. 8 - Prob. 8.34CPCh. 8 - The following reaction of A3 molecules is...Ch. 8 - Prob. 8.36SPCh. 8 - What is internal energy?Ch. 8 - Prob. 8.38SPCh. 8 - Assume that the kinetic energy of a 1400 kg car...Ch. 8 - Prob. 8.40SPCh. 8 - The addition of H2 to CC double bonds is an...Ch. 8 - Prob. 8.42SPCh. 8 - Prob. 8.43SPCh. 8 - Prob. 8.44SPCh. 8 - Prob. 8.45SPCh. 8 - Prob. 8.46SPCh. 8 - Does a measurement carried out in a bomb...Ch. 8 - Prob. 8.48SPCh. 8 - Prob. 8.49SPCh. 8 - Prob. 8.50SPCh. 8 - When 0.187 g of benzene, C6H6, is burned in a bomb...Ch. 8 - When a solution containing 8.00 g of NaOH in 50.0...Ch. 8 - Prob. 8.53SPCh. 8 - Prob. 8.54SPCh. 8 - Prob. 8.55SPCh. 8 - Prob. 8.56SPCh. 8 - Prob. 8.57SPCh. 8 - Prob. 8.58SPCh. 8 - Prob. 8.59SPCh. 8 - Prob. 8.60SPCh. 8 - Prob. 8.61SPCh. 8 - Used in welding metals, the reaction of acetylene...Ch. 8 - Prob. 8.63SPCh. 8 - The familiar ether used as an anesthetic agent is...Ch. 8 - How much energy in kilojoules is required to...Ch. 8 - Prob. 8.66SPCh. 8 - Prob. 8.67SPCh. 8 - Prob. 8.68SPCh. 8 - Prob. 8.69SPCh. 8 - Prob. 8.70SPCh. 8 - Prob. 8.71SPCh. 8 - Prob. 8.72SPCh. 8 - Prob. 8.73SPCh. 8 - Prob. 8.74SPCh. 8 - Prob. 8.75SPCh. 8 - Prob. 8.76SPCh. 8 - Prob. 8.77SPCh. 8 - Prob. 8.78SPCh. 8 - Prob. 8.79SPCh. 8 - Prob. 8.80SPCh. 8 - Prob. 8.81SPCh. 8 - Styrene (C8H8), the precursor of polystyrene...Ch. 8 - Prob. 8.83SPCh. 8 - Prob. 8.84SPCh. 8 - Prob. 8.85SPCh. 8 - Prob. 8.86SPCh. 8 - Prob. 8.87SPCh. 8 - Use the bond dissociation energies in Table 8.3 on...Ch. 8 - Use the bond dissociation energies in Table 8.3 to...Ch. 8 - Prob. 8.90SPCh. 8 - Prob. 8.91SPCh. 8 - Prob. 8.92SPCh. 8 - Prob. 8.93SPCh. 8 - Prob. 8.94SPCh. 8 - Prob. 8.95SPCh. 8 - Prob. 8.96SPCh. 8 - Prob. 8.97SPCh. 8 - Prob. 8.98SPCh. 8 - Prob. 8.99SPCh. 8 - Prob. 8.100SPCh. 8 - Prob. 8.101SPCh. 8 - Prob. 8.102SPCh. 8 - Tell whether reactions with the following values...Ch. 8 - Prob. 8.104SPCh. 8 - Prob. 8.105SPCh. 8 - Prob. 8.106SPCh. 8 - Prob. 8.107SPCh. 8 - Prob. 8.108SPCh. 8 - Prob. 8.109SPCh. 8 - When 1.50 g of magnesium metal is allowed to react...Ch. 8 - Use the data in Appendix B to find standard...Ch. 8 - Prob. 8.112CHPCh. 8 - The boiling point of a substance is defined as the...Ch. 8 - What is the melting point of benzene in kelvin if...Ch. 8 - Metallic mercury is obtained by heating the...Ch. 8 - Prob. 8.116CHPCh. 8 - Methanol (CH3OH) is made industrially in two steps...Ch. 8 - Isooctane, C8H18, is the component of gasoline...Ch. 8 - We said in Section 8.1 that the potential energy...Ch. 8 - For a process to be spontaneous, the total entropy...Ch. 8 - Set up a Hesss law cycle, and use the following...Ch. 8 - Prob. 8.122CHPCh. 8 - Prob. 8.123CHPCh. 8 - Prob. 8.124CHPCh. 8 - Citric acid has three dissociable hydrogens. When...Ch. 8 - Prob. 8.126CHPCh. 8 - Imagine that you dissolve 10.0 g of a mixture of...Ch. 8 - Prob. 8.128CHPCh. 8 - Prob. 8.129MPCh. 8 - Phosgene, COCl2(g), is a toxic gas used as an...Ch. 8 - Prob. 8.131MPCh. 8 - (a) Write a balanced equation for the reaction of...Ch. 8 - Prob. 8.133MPCh. 8 - Reaction of gaseous fluorine with compound X...
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