a) Interpretation: The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified. Concept introduction: In addition reactions small molecules like HCl, H 2 O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”. To state: Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Question

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Answer 1

Question

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

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Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

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Answer 3

Question

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

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Answer 4

Question

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

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Answer 5

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

Answer 6

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Answer 7

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Answer 8

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Answer 9

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Answer 10

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Answer 11

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Answer 12

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

Answer 13

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

Answer 14

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Answer 25

Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2P Ch. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5P Ch. 7.3 - Prob. 6P Ch. 7.3 - Prob. 7P Ch. 7.4 - Prob. 8P Ch. 7.4 - Prob. 9P Ch. 7.4 - Prob. 10P

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