a) Interpretation: To assign E or Z configuration for the compound given. Concept introduction: The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration. To assign: The configuration for the compound given as E or Z.

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Answer 1

Question

Chapter 7.5, Problem 13P

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

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In the video, we looked at the absorbance of a certain substance and how it varies depending on what wavelength of light we are looking at. Below is a similar scan of a different substance. What color BEST describes how this substance will appear? Absorbance (AU) Violet Blue Green Orange 1.2 1.0- 0.8- 0.6- 0.4- 0.2 0.0 450 500 550 600 650 700 Wavelength (nm) violet indigo blue green yellow orange red Red O Cannot tell from this information In the above graph, what causes -450 nm wavelength of light to have a higher absorbance than light with a -550 nm wavelength? Check all that are true. The distance the light travels is different The different data points are for different substances The concentration is different at different times in the experiment Epsilon (molar absortivity) is different at different wavelengths

5. a. Data were collected for Trial 1 to determine the molar mass of a nonvolatile solid solute when dissolved in cyclo- hexane. Complete the table for the analysis (See Report Sheet). Record calculated values with the correct number of significant figures. B. Freezing Point of Cyclohexane plus Calculation Zone Unknown Solute 2. Mass of cyclohexane (g) 10.14 Part C.4 3. Mass of added solute (g) 0.255 C. Calculations 1. k; for cyclohexane (°C⚫ kg/mol) 20.0 2. Freezing point change, AT, (°C) 3.04 Part C.6 3. Mass of cyclohexane in solution (kg) 4. Moles of solute, total (mol) Show calculation. 5. Mass of solute in solution, total (g) 6. Molar mass of solute (g/mol) Show calculation.

Answer 2

Question

Chapter 7.5, Problem 13P

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

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Answer 3

Question

Chapter 7.5, Problem 13P

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

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Answer 4

Question

Chapter 7.5, Problem 13P

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

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Answer 5

Chapter 7.5, Problem 13P

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 6

Chapter 7.5, Problem 13P

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 7

Chapter 7.5, Problem 13P

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 8

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 9

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 10

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 11

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 12

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 13

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The two groups attached to the carbons in double bond are to be ranked first. The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on the opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 14

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Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2P Ch. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5P Ch. 7.3 - Prob. 6P Ch. 7.3 - Prob. 7P Ch. 7.4 - Prob. 8P Ch. 7.4 - Prob. 9P Ch. 7.4 - Prob. 10P

Solution Summary: The author explains how the two groups attached to the carbons in double bond are to be ranked first. The atom with highest atomic number gets the higher rank.

Chapter 7 Solutions