a) Interpretation: The structure of more stable carbocation obtainable by the rearrangement of the n-butylcarbocation is to be proposed. Concept introduction: The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon. To propose: The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Question

Laser. Indicate the relationship between metastable state and stimulated emission.

Answer 1

Question

Chapter 7.SE, Problem 60AP

Interpretation Introduction

a)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the n-butylcarbocation is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Interpretation Introduction

b)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation can rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Interpretation Introduction

c)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

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Laser. Indicate the relationship between metastable state and stimulated emission.

The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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Answer 2

Question

Chapter 7.SE, Problem 60AP

Interpretation Introduction

a)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the n-butylcarbocation is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Interpretation Introduction

b)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation can rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Interpretation Introduction

c)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

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Answer 3

Question

Chapter 7.SE, Problem 60AP

Interpretation Introduction

a)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the n-butylcarbocation is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Interpretation Introduction

b)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation can rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Interpretation Introduction

c)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

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Answer 4

Question

Chapter 7.SE, Problem 60AP

Interpretation Introduction

a)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the n-butylcarbocation is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Interpretation Introduction

b)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation can rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Interpretation Introduction

c)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

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Answer 5

Chapter 7.SE, Problem 60AP

Interpretation Introduction

a)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the n-butylcarbocation is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Interpretation Introduction

b)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation can rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Interpretation Introduction

c)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Answer 6

Chapter 7.SE, Problem 60AP

Interpretation Introduction

a)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the n-butylcarbocation is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Answer 7

Chapter 7.SE, Problem 60AP

Interpretation Introduction

a)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the n-butylcarbocation is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Answer 8

Interpretation Introduction

b)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation can rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Answer 9

Interpretation Introduction

b)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation can rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Answer 10

Interpretation Introduction

c)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Answer 11

Interpretation Introduction

c)

Interpretation:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given is to be proposed.

Concept introduction:

The stability of carbocations are in the order tertiary > secondary > primary. A carbocation will rearrange to a more stable carbocation either by a hydride shift or by an alkyl shift from adjacent carbon.

To propose:

The structure of more stable carbocation obtainable by the rearrangement of the carbocation given.

Answer 12

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Answer 23

Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2P Ch. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5P Ch. 7.3 - Prob. 6P Ch. 7.3 - Prob. 7P Ch. 7.4 - Prob. 8P Ch. 7.4 - Prob. 9P Ch. 7.4 - Prob. 10P

Solution Summary: The author proposes the structure of more stable carbocation obtainable by the rearrangement of the n-butylcarbocated.

Chapter 7 Solutions