Given that the isobutyl cation spontaneously rearranges to the tert -butyl cation by a hydride shit. The nature of the rearrangement exergonic or endergonic is to be stated. Applying Hammond postulate, how the transition state for the hydride shift might look like is to be drawn. Concept introduction: The stabilities of the carbocations are in the order tertiary > secondary > primary. The conversion of a less stable system in to a more stable system will take place readily and it will be an exergonic process. According to Hammond postulate, the transition state of an exergonic reaction will resemble the structure of the reactants. To state: Whether the spontaneous rearrangement of isobutyl cation to the tert -butyl cation by a hydride shit is exergonic or endergonic.Further to draw, by applying Hammond postulate, the transition state for the hydride shift.

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1/2 - 51% + » GAY Organic Reactions Assignment /26 Write the type of reaction that is occurring on the line provided then complete the reaction. Only include the major products and any byproducts (e.g. H₂O) but no minor products. Please use either full structural diagrams or the combination method shown in the lesson. Skeletal/line diagrams will not be accepted. H3C 1. 2. CH3 A Acid OH Type of Reaction: NH Type of Reaction: + H₂O Catalyst + HBr 3. Type of Reaction: H3C 4. Type Reaction: 5. H3C CH2 + H2O OH + [0] CH3 Type of Reaction: 6. OH CH3 HO CH3 + Type of Reaction: 7. Type of Reaction: + [H]

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Question

Chapter 7.SE, Problem 68AP

Interpretation Introduction

Interpretation:

Given that the isobutyl cation spontaneously rearranges to the tert-butyl cation by a hydride shit. The nature of the rearrangement exergonic or endergonic is to be stated. Applying Hammond postulate, how the transition state for the hydride shift might look like is to be drawn.

Concept introduction:

The stabilities of the carbocations are in the order tertiary > secondary > primary. The conversion of a less stable system in to a more stable system will take place readily and it will be an exergonic process. According to Hammond postulate, the transition state of an exergonic reaction will resemble the structure of the reactants.

To state:

Whether the spontaneous rearrangement of isobutyl cation to the tert-butyl cation by a hydride shit is exergonic or endergonic.Further to draw, by applying Hammond postulate, the transition state for the hydride shift.

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