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- Which of the following pairs represent resonance structures of each other? O- O- O-- :0: H₂C-C-CH3 H₂C=CH-CH₂ H NH₂ 0 :OH H₂C-C=CH₂ NH₂ H3C-CH=CH₂ -H dCH3 5 OH H3C `CH3 2-isopropyl-5-methylcyclohexanol There are four cis,trans isomers for 2-isopropyl-5-methylcyclohexanol, where the cis,trans designations of the substituents are made relative to the OH group: • up, up, up (cis,cis) • up, up, down (cis,trans) • up, down, down (trans,cis) • up, down, up (trans,trans) Consider the most stable chair for each of these isomers, and then draw the most stable and least stable isomer based on a comparison of the best chair for each one. • To simplify matters, consider only axial vs equatorial energies of the groups (i.e. do not worry about the interactions between the groups, which in reality is also important). • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • You do not have to explicitly draw H atoms. • Use “flat" representations of rings, not chairs, in your drawing.Explain why these two molecules are not isomers:
- Chloramphenicol is a broad-spectrum antibiotic that is particularly useful against typhoid fever. What is the configuration of each asymmetric carbon in chloramphenicol? HỌ H c-c-CH,OH NHCCHCI, NO2 chloramphenicol-C-Br+ HD H2O 250 (cH,CH>),C-Br (CH3CH2), -C- Br 750Convert the following structure to a skeletal drawing and give its molecular formula. Br H H -c Η | H H 3-bromo-1-cyclopentene
- 1 a Name each of the following compounds: D H3C- A CH3 CH3 HạC—CH—CH, NH, C−CH,NH, CH 3 E B H3C- CH3 HỌC—-CH-CHNH, CH₂ CH3 H₂C-C=C- -NH₂ CH3 F Oe -NH₂ -CHz—CHz—NHz• How do you differentiate the following pair of compounds by IR? H, H2 H H,c-Cc-CH, H2 1 H;C CH3 H2 H2 -CH3 H2 2 H,C H2 H2 H,c-Cc-CH, H2 H,c-CCECH H;C 4Using the numbering scheme below, which carbons are primary (1°)? U T [ n ¶ | 3 U 1 2 3 4 5 6 2 07 8 6 8