Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 7, Problem 62P

(a)

Interpretation Introduction

Interpretation: The mechanism and the major product formed in the reaction of a secondary haloalkane in the polar aprotic solvent needs to be determined if the nucleophile is N3 .

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The mechanism and the major product formed in the reaction of a secondary haloalkane in the polar aprotic solvent needs to be determined if the nucleophile is NH2 .

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The mechanism and the major product formed in the reaction of a secondary haloalkane in the polar aprotic solvent needs to be determined if the nucleophile is ammonia.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The mechanism and the major product formed in the reaction of a secondary haloalkane in the polar aprotic solvent needs to be determined if the nucleophile is HSe-.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The mechanism and the major product formed in the reaction of a secondary haloalkane in the polar aprotic solvent needs to be determined if the nucleophile is fluoride ion.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(f)

Interpretation Introduction

Interpretation: The mechanism and the major product formed in the reaction of a secondary haloalkane in the polar aprotic solvent needs to be determined if the nucleophile is C6H5O .

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(g)

Interpretation Introduction

Interpretation: The mechanism and the major product formed in the reaction of a secondary haloalkane in the polar aprotic solvent needs to be determined if the nucleophile is PH3.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(h)

Interpretation Introduction

Interpretation: The mechanism and the major product formed in the reaction of a secondary haloalkane in the polar aprotic solvent needs to be determined if the nucleophile is NH2OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(i)

Interpretation Introduction

Interpretation: The mechanism and the major product formed in the reaction of a secondary haloalkane in the polar aprotic solvent needs to be determined if the nucleophile is NCS-.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

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