The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S N 1 or S N 2 process should be indicated. Concept Introduction: The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction. The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction. The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S N 1 and S N 2 reaction. The reaction which takes place in one step is known as S N 2 reaction whereas reaction which takes place in two steps is known as S N 1 reaction.

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Answer 1

Question

Chapter 7, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(b)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(c)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(d)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

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Dr. Mendel asked his BIOL 260 class what their height was and what their parent's heights were. He plotted that data in the graph below to determine if height was a heritable trait. A. Is height a heritable trait? If yes, what is the heritability value? (2 pts) B. If the phenotypic variation is 30, what is the variation due to additive alleles? (2 pts) Offspring Height (Inches) 75 67.5 60 52.5 y = 0.9264x + 4.8519 55 60 65 MidParent Height (Inches) 70 75 12pt v V Paragraph B IUA > AT2 v V

Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Chapter 7, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(b)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(c)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(d)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

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Answer 3

Question

Chapter 7, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(b)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(c)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(d)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

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Answer 4

Question

Chapter 7, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(b)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(c)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(d)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

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Answer 5

Chapter 7, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(b)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(c)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

(d)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

Answer 6

Chapter 7, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

Answer 7

Chapter 7, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The products of the following reaction should be drawn along with the mechanism for the formation. Whether the product arises through S_N1 or S_N2 process should be indicated.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as S_N1 and S_N2 reaction.

The reaction which takes place in one step is known as S_N2 reaction whereas reaction which takes place in two steps is known as S_N1 reaction.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 7.1 - Prob. 7.1E Ch. 7.2 - Prob. 7.2E Ch. 7.3 - Prob. 7.3E Ch. 7.3 - Prob. 7.5TIY Ch. 7.4 - Prob. 7.7TIY Ch. 7.5 - Prob. 7.9TIY Ch. 7.6 - Prob. 7.10E Ch. 7.7 - Prob. 7.11E Ch. 7.7 - Prob. 7.12E Ch. 7.7 - Prob. 7.13E

Solution Summary: The author explains that the products of the following reaction should be drawn along with the mechanism for the formation.

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Chapter 7 Solutions