EBK ESSENTIAL ORGANIC CHEMISTRY
EBK ESSENTIAL ORGANIC CHEMISTRY
3rd Edition
ISBN: 9780100659469
Author: Bruice
Publisher: YUZU
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Chapter 6.3, Problem 6P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds has to be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr has to be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds has to be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds has to be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds has to be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds has to be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

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14.46 Draw a stepwise mechanism for the following reaction. HBr ROOR Br + Br
Show work..don't give Ai generated solution....
14.47 Addition of HCI to alkene X forms two alkyl halides Y and Z. exocyclic C=C X HCI CI Y + CI Z a. Label Y and Z as a 1,2-addition product or a 1,4-addition product. b.Label Y and Z as the kinetic or thermodynamic product and explain why. c. Explain why addition of HCI occurs at the indicated C=C (called an exocyclic double bond), rather than the other C=C (called an endocyclic double bond).

Chapter 6 Solutions

EBK ESSENTIAL ORGANIC CHEMISTRY

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