Calculate the overall energy change in kilojoules per mole for the formation of CaCl( s ) from the elements. The following data are needed: E ea for Cl ( g ) = − 348 .6 kJ/mol E i1 for Ca ( g ) = + 589 . 8 kJ/mol E i2 for Ca ( g ) = + 1145 kJ/mol Heat of sublimation for Cs ( s ) = + 1 78 . 2 kJ/mol Bond dissociation energy for Cl 2 ( g ) = + 243 kJ per mol of Cl 2 ( g ) Lattice energy for CaCl 2 ( s ) = + 2258 kJ/mol Lattice energy for CaCl ( s ) = + 717 kJ/mol ( estimated )
Calculate the overall energy change in kilojoules per mole for the formation of CaCl( s ) from the elements. The following data are needed: E ea for Cl ( g ) = − 348 .6 kJ/mol E i1 for Ca ( g ) = + 589 . 8 kJ/mol E i2 for Ca ( g ) = + 1145 kJ/mol Heat of sublimation for Cs ( s ) = + 1 78 . 2 kJ/mol Bond dissociation energy for Cl 2 ( g ) = + 243 kJ per mol of Cl 2 ( g ) Lattice energy for CaCl 2 ( s ) = + 2258 kJ/mol Lattice energy for CaCl ( s ) = + 717 kJ/mol ( estimated )
Solution Summary: The author describes the steps required to draw Born-Haber cycle of ionic solids from its constituent elements.
Calculate the overall energy change in kilojoules per mole for the formation of CaCl(s) from the elements. The following data are needed:
E
ea
for Cl
(
g
)
=
−
348
.6 kJ/mol
E
i1
for Ca
(
g
)
=
+
589
.
8 kJ/mol
E
i2
for Ca
(
g
)
=
+
1145 kJ/mol
Heat of sublimation for Cs
(
s
)
=
+
1
78
.
2 kJ/mol
Bond dissociation energy for Cl
2
(
g
)
=
+
243 kJ
per mol of Cl
2
(
g
)
Lattice energy for CaCl
2
(
s
)
=
+
2258
kJ/mol
Lattice energy for CaCl
(
s
)
=
+
717
kJ/mol
(
estimated
)
How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
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Lanthanoids and its Position in Periodic Table - D and F Block Elements - Chemistry Class 12; Author: Ekeeda;https://www.youtube.com/watch?v=ZM04kRxm6tY;License: Standard YouTube License, CC-BY