Principles of General Chemistry
Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 6, Problem 6.64P

(a)

Interpretation Introduction

Interpretation:Energy released by combustion of octane is to be calculated.

Concept Introduction : The reaction for combustion of octane is:

  2C8H18+25O216CO2+18H2O

Combustion is basically the reaction of a substance with oxygen. In the above reactionthe combustion of octane gives  CO2 and H2O as the product.

(b)

Interpretation Introduction

Interpretation:The cruising range of the car on a full tank is to be determined.

Concept Introduction : Cruise range covered by car depends on the amount of chemical energy transferred to the surrounding by the system.

(c)

Interpretation Introduction

Interpretation:Miles of the car is to be related if the actual cruising mile is 455 with respect to (b).

Concept Introduction : Chemical energy is the potential of chemical substance to undergo a chemical reaction.Work done is directly proportional to the chemical energy provided.

The work done depends on the energy transferred to the surrounding by the system.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

Chapter 6 Solutions

Principles of General Chemistry

Ch. 6 - Why can we measure only changes in enthalpy, not...Ch. 6 - Draw an enthalpy diagram for a general exothermic...Ch. 6 - Prob. 6.13PCh. 6 - Prob. 6.14PCh. 6 - Prob. 6.15PCh. 6 - Write a balanced equaĂ¼on and draw an approximate...Ch. 6 - Write a balanced equation and draw an approximate...Ch. 6 - The circles represent a phase change at constant...Ch. 6 - The scenes below represent a physical change...Ch. 6 - What data do you need to determine the specific...Ch. 6 - Is the specific heat capacity of a substance an...Ch. 6 - Find q when 22.0 g of water is heated from 25.0C...Ch. 6 - Prob. 6.23PCh. 6 - A 295-g aluminum engine part at an initial...Ch. 6 - A 27.7-g sample of the radiator coolant ethylene...Ch. 6 - Two iron bolts of equal mass-one at 100.C, the...Ch. 6 - Prob. 6.27PCh. 6 - When 155 mL of water at 26C is mixed with 75 mL of...Ch. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - When 25.0 mL of 0.500MH2SO4 is added to 25.0 mL of...Ch. 6 - Would you expect O2(g)20(g) to have a positive or...Ch. 6 - Is H positive or negative when 1 mol of water...Ch. 6 - Prob. 6.35PCh. 6 - Consider the following balanced thermochemical...Ch. 6 - When 1 mol of NO(g) forms from Its elements, 90.29...Ch. 6 - Prob. 6.38PCh. 6 - Liquid hydrogen peroxide, an oxidizing agent in...Ch. 6 - Prob. 6.40PCh. 6 - Most ethylene (C2H4), the starting material for...Ch. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - Calculate H for Ca(s)+12O2(g)+CO2(g)CaCO3(s) Given...Ch. 6 - Calculate H for 2NOCl(g)N2(g)+O2(g)+Cl2(g) given...Ch. 6 - Write the balanced overall equation (equation 3)...Ch. 6 - Write the balanced overall equation (equation 3)...Ch. 6 - Diamond and graphite are two crystalline forms of...Ch. 6 - Prob. 6.49PCh. 6 - Prob. 6.50PCh. 6 - Use Table 6.3 or Appendix B to write a balanced...Ch. 6 - Prob. 6.52PCh. 6 - Calculate Hrxno for each of the following:...Ch. 6 - Calculate Hrxno for each of the following:...Ch. 6 - Copper(I) oxide can be oxidized to copperr (II)...Ch. 6 - Prob. 6.56PCh. 6 - Nitroglycerine, C3H5(NO3)3(l), a powerful...Ch. 6 - The common lead-acid car battery produces a large...Ch. 6 - Stearic acid (C18H36O2) is a fatty acid, a...Ch. 6 - A ballonist begins a trip in a helium-filled...Ch. 6 - Prob. 6.61PCh. 6 - Prob. 6.62PCh. 6 - Prob. 6.63PCh. 6 - Prob. 6.64PCh. 6 - Four 50.-g sample of different liquids are placed...Ch. 6 - When simple sugars, called monosaccharides, link...Ch. 6 - Reaction of gaseous CIF with F2 yields liquid...Ch. 6 - Prob. 6.68PCh. 6 - When organic matter decomposes under oxygen-free...Ch. 6 - The heat of atomization (Hatomo) is the heat...Ch. 6 - Prob. 6.71PCh. 6 - Prob. 6.72PCh. 6 - An aqueous wastes stream with a maximum...Ch. 6 - Kerosene, a common space-heater fuel, is a mixture...Ch. 6 - Prob. 6.75PCh. 6 - Phosphorus pentachloride is used in the industrial...Ch. 6 - Prob. 6.77PCh. 6 - Silicon tetrachloride is produced annually on the...Ch. 6 - Prob. 6.79PCh. 6 - You want to determine Ho for the reaction...Ch. 6 - Prob. 6.81PCh. 6 - Prob. 6.82PCh. 6 - Liquid methanol (CH3OH) can be used as an...Ch. 6 - How much heat is released when 25.0 g of methane...
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