Interpretation:
The products and the mechanism of formation of products by
Concept introduction:
Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon or a functional group is substituted by any other functional group is called substitution reaction.
Elimination reaction: A reaction in which two substituent groups are detached and a double bond is formed is called elimination reaction.
E1 and E2 are the two types of elimination reaction.
Nucleophilic substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon or a functional group is substituted by any nucleophile is called nucleophilic substitution reaction.
A nucleophile is a molecule or atom with most negative charge.
There are two types of nucleophilic substitution reactions:
Want to see the full answer?
Check out a sample textbook solutionChapter 6 Solutions
Organic Chemistry
- Give the structures of the free-radical intermediates in the peroxide-initiated reaction of HBr with the following alkene. Include all lone-pair electrons and unpaired electrons. Hint: the radicals do not coexist in the same mechanistic step. сCH2 Hint: One organic radical and one inorganic radical.arrow_forwardComplete the following reactions: indicate the mechanism (SN1 or SN2). If the reaction does not proceed, indicate so and the reason as to why it would not.arrow_forwardМЕСНANISMS 1,2-epoxy-1-methylcyclopentane undergoes both acid-catalyzed and base-catalyzed opening of the epoxide ring to form two different products. > Using ethanol as the solvent and an appropriate acid, show the steps in the acid catalyzed mechanism, writing structures for all products of the steps. Circle the major product(s). > Using ethanol as the solvent and an appropriate base, show the steps in the base- catalyzed mechanism, writing structures for all products of the steps. Circle the major product(s). 1,2-epoxy-1-methylcyclopentane CH3arrow_forward
- Can someone pleae help me with this question? The question is: Draw a reasonable mechanism for this reaction. All compounds involved in each stage of the mechanism must be enclosed in a box, and each box must be connected to the next one with a straight arrow. Use electron-flow arrows to show the movement of electrons in each step.arrow_forward5) Predict the major product or the necessary reagent or reactant to complete each of the following reactions. In the box before each reaction, indicate the mechanism followed by the reaction. (Free radical (FR), SN2, SN1). (e) (f) CH₂OH (e) 1 2 (f) (g) (h) -Br predict the starting compound Cl₂ heat CH3CH₂O + Na K+1 CH3 H7 H + KBrarrow_forward(b) Consider the reaction of 1-bromobutane with a large excess of ammonia (NH3). Draw the reactants, the transition state, andthe products. Note that the initial product is the salt of an amine (RNH3+ Br - ), which is deprotonated by the excess ammonia to give the amine.arrow_forward
- Give the product/s for the following reaction and indicate what mechanism is involved in the formation of such product/s as SN1, SN2, E1, E2. CH3CH=CHCl + NaNH2arrow_forwardSuppose you are told that each reaction is a substitution reaction but are not told the mechanism. Describe how you could conclude from the structure of the haloalkane, the nucleophile, and the solvent that each reaction is an SN2 reaction.arrow_forwardIn attempting to make 2-bromo-2-methyl-propane from 2-methyl-propene, as shown below, you used a dilute aqueous solution of hydrobromic acid. Upon analysis of the isolated product, you realize there is a major unwanted by-product. Br a) Based on the reaction conditions used, predict the major by-product and show a mechanism for its formation. b) What should be changed in the reaction conditions described in order to completely avoid the formation of the unwanted by-product?arrow_forward
- Suppose you are told that each reaction is a substitution reaction but are not told the mechanism. Describe how you could conclude from the structure of the haloalkane, the nucleophile, and the solvent that each reaction is an SN2 reaction.arrow_forwardI cannot figure out this question about ozonolysis of an alkene? There are two double carbon bonds to choose from on the ring, so how do we know what is being acted on? (if that makes sense) Thank you!arrow_forwardWhich reaction(s) would you use to convert Cyclohexanone to Methylenecyclohexane (A) and 1-Methylcyclohexane (B)? Hint: The single step process A gives product A exclusively in high yield. The two-step process B gives the B as the major product. Answer must be in this format: In the first text box, write A) name of the one step reaction. In the second text box, write B) name of the reagent or reaction for the first step: name of the reagent or reaction for the second step. CHarrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning