
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
7th Edition
ISBN: 9781305081086
Author: STOKER, H. Stephen
Publisher: Brooks Cole
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 5.6, Problem 5QQ
Interpretation Introduction
Interpretation:
The number of different types of bond that is present in Lewis structure of molecule
Concept Introduction:
Lewis structure clearly depicts the bonding and nonbonding electrons in the atom. This is only partially useful for the molecule that contains one or more multiple bonds and when coordinate covalent bond is present in the molecule. For drawing Lewis structure a systematic procedure is followed. They are,
- The total number of valence electrons that is present in molecule is calculated by adding all the valence electrons of the atoms present in the molecule.
- The chemical symbols for the atoms that is present in the molecule is written in the order that they are bonded. After this a single covalent bond is placed between each atoms as two electrons.
- The nonbonding electrons are added to each atom that is bonded to the central atom so that it contains octet of electrons. For hydrogen alone the “octet” is only two electrons.
- The remaining electrons has to be placed on the central atom in the structure.
- If there is no octet of electrons present in the central atom, then use one or more pairs of nonbonding electrons that is bonded to the central atom to form double or triple bonds.
- The total number of electrons has to be counted and it has to be confirmed whether the count is same as that of the number of valence electrons that is available for bonding.
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Search Results
Search Results
Best Free Coursehero Unlo x b Success Confirmation of Q
aleks.com/alekscgi/x/sl.exe/10_u-lgNslkr7j8P3jH-IQs_pBan HhvlTCeeBZbufu BYTIOHz7m7D3ZcHYUt80XL-5alyVpwDXM TEZayFYCav
States of Matter
Using a phase diagram to find a phase transition temperature or pressure
Use the phase diagram of Substance X below to find the temperature at which X turns to a gas, if the pressure above the solid is 3.7 atm.
pressure (atm)
0.
32-
16
solid
liquid
gas
200
temperature (K)
Note: your answer must be within 20 °C of the exact answer to be graded correct.
Дос
X
Consider the reaction below to answer the following questions:
Acetoacetic ester can be prepared by the Claisen self-condensation reaction of ethyl acetate.
1. NaOEt, EtOH
H&C
OCH CH3 2 H30
H3C
CH2
OCH2CH3
A. Write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and
draw all intermediate structures.
B. Ethyl acetate can be prepared from ethanol as the only organic starting material. Show all reagents
and structures for all intermediates in this preparation.
C. Give the structures of the ester precursors for the following Claisen condensation product and
formulate the reaction.
OEt
Use the phase diagram of Substance X below to find the temperature at which X turns to a gas, if the pressure above the solid is 3.7 atm.
pressure (atm)
32
16
solid
liquid
gas
0
0
200
temperature (K)
Note: your answer must be within 20 °C of the exact answer to be graded correct.
Шос
☑
ك
Chapter 5 Solutions
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
Ch. 5.1 - Covalent bond formation most often involves...Ch. 5.1 - Which of the following concepts is closely...Ch. 5.1 - Prob. 3QQCh. 5.1 - Prob. 4QQCh. 5.2 - Prob. 1QQCh. 5.2 - Prob. 2QQCh. 5.2 - Prob. 3QQCh. 5.2 - Prob. 4QQCh. 5.2 - Prob. 5QQCh. 5.2 - Prob. 6QQ
Ch. 5.3 - Prob. 1QQCh. 5.3 - Prob. 2QQCh. 5.3 - Prob. 3QQCh. 5.3 - Prob. 4QQCh. 5.3 - Prob. 5QQCh. 5.4 - Prob. 1QQCh. 5.4 - Prob. 2QQCh. 5.4 - Prob. 3QQCh. 5.5 - Which of the following is an incorrect statement...Ch. 5.5 - Prob. 2QQCh. 5.5 - Prob. 3QQCh. 5.6 - Prob. 1QQCh. 5.6 - Prob. 2QQCh. 5.6 - Prob. 3QQCh. 5.6 - Prob. 4QQCh. 5.6 - Prob. 5QQCh. 5.7 - Prob. 1QQCh. 5.7 - Prob. 2QQCh. 5.7 - Prob. 3QQCh. 5.8 - Prob. 1QQCh. 5.8 - In VSEPR theory, an angular molecular geometry is...Ch. 5.8 - Prob. 3QQCh. 5.8 - Prob. 4QQCh. 5.8 - Prob. 5QQCh. 5.9 - Prob. 1QQCh. 5.9 - Prob. 2QQCh. 5.9 - Prob. 3QQCh. 5.9 - Prob. 4QQCh. 5.10 - Prob. 1QQCh. 5.10 - Prob. 2QQCh. 5.10 - Prob. 3QQCh. 5.10 - As the difference in electronegativity between two...Ch. 5.10 - Prob. 5QQCh. 5.10 - Prob. 6QQCh. 5.11 - Prob. 1QQCh. 5.11 - Prob. 2QQCh. 5.11 - Prob. 3QQCh. 5.11 - Prob. 4QQCh. 5.11 - Prob. 5QQCh. 5.12 - Prob. 1QQCh. 5.12 - Prob. 2QQCh. 5.12 - Prob. 3QQCh. 5.12 - Prob. 4QQCh. 5.12 - Prob. 5QQCh. 5.12 - Prob. 6QQCh. 5 - Contrast the types of elements involved in ionic...Ch. 5 - Contrast the mechanisms by which ionic and...Ch. 5 - Prob. 5.3EPCh. 5 - Prob. 5.4EPCh. 5 - Indicate whether or not covalent bond formation is...Ch. 5 - Indicate whether or not covalent bond formation is...Ch. 5 - Draw Lewis structures to illustrate the covalent...Ch. 5 - Draw Lewis structures to illustrate the covalent...Ch. 5 - How many nonbonding electron pairs are present in...Ch. 5 - How many nonbonding electron pairs are present in...Ch. 5 - The component elements for four binary molecular...Ch. 5 - The component elements for four binary molecular...Ch. 5 - Specify the number of single, double, and triple...Ch. 5 - Specify the number of single, double, and triple...Ch. 5 - Convert each of the Lewis structures in Problem...Ch. 5 - Convert each of the Lewis structures in Problem...Ch. 5 - Prob. 5.17EPCh. 5 - Prob. 5.18EPCh. 5 - Prob. 5.19EPCh. 5 - Identify the Period 3 nonmetal that would normally...Ch. 5 - How many valence electrons do atoms possess that...Ch. 5 - Prob. 5.22EPCh. 5 - What aspect of the following Lewis structure...Ch. 5 - What aspect of the following Lewis structure...Ch. 5 - Identify the coordinate covalent bond(s) present,...Ch. 5 - Identify the coordinate covalent bond(s) present,...Ch. 5 - Without actually drawing the Lewis structure,...Ch. 5 - Without actually drawing the Lewis structure,...Ch. 5 - Prob. 5.29EPCh. 5 - Prob. 5.30EPCh. 5 - Draw the Lewis structure for each of the molecules...Ch. 5 - Draw the Lewis structure for each of the molecules...Ch. 5 - Draw Lewis structures to illustrate the bonding in...Ch. 5 - Draw Lewis structures to illustrate the bonding in...Ch. 5 - How many electron dots should appear in the Lewis...Ch. 5 - Prob. 5.36EPCh. 5 - Draw Lewis structures for the following polyatomic...Ch. 5 - Draw Lewis structures for the following polyatomic...Ch. 5 - Draw Lewis structures for the following compounds...Ch. 5 - Draw Lewis structures for the following compounds...Ch. 5 - Draw Lewis structures for the following molecules...Ch. 5 - Draw Lewis structures for the following molecules...Ch. 5 - In which of the following pairs of diatomic...Ch. 5 - In which of the following pairs of diatomic...Ch. 5 - Prob. 5.45EPCh. 5 - What is the molecular geometry associated with...Ch. 5 - Specify the molecular geometry of each of the...Ch. 5 - Specify the molecular geometry of each of the...Ch. 5 - Prob. 5.49EPCh. 5 - Prob. 5.50EPCh. 5 - Prob. 5.51EPCh. 5 - Prob. 5.52EPCh. 5 - Prob. 5.53EPCh. 5 - Prob. 5.54EPCh. 5 - Using VSEPR theory, predict the molecular geometry...Ch. 5 - Using VSEPR theory, predict the molecular geometry...Ch. 5 - Prob. 5.57EPCh. 5 - Specify both the VSEPR electron group geometry...Ch. 5 - Prob. 5.59EPCh. 5 - Prob. 5.60EPCh. 5 - Using a periodic table, but not a table of...Ch. 5 - Using a periodic table, but not a table of...Ch. 5 - Prob. 5.63EPCh. 5 - Prob. 5.64EPCh. 5 - Place + above the atom that is relatively positive...Ch. 5 - Place + above the atom that is relatively positive...Ch. 5 - Rank the following bonds in order of increasing...Ch. 5 - Rank the following bonds in order of increasing...Ch. 5 - Classify each of the following bonds as nonpolar...Ch. 5 - Classify each of the following bonds as nonpolar...Ch. 5 - Prob. 5.71EPCh. 5 - Prob. 5.72EPCh. 5 - Fill in the blanks in each line of the following...Ch. 5 - Fill in the blanks in each line of the following...Ch. 5 - Four hypothetical elements, A, B, C, and D, have...Ch. 5 - Four hypothetical elements, A, B, C, and D, have...Ch. 5 - Indicate whether each of the following...Ch. 5 - Prob. 5.78EPCh. 5 - Indicate whether each of the following triatomic...Ch. 5 - Indicate whether each of the following triatomic...Ch. 5 - Indicate whether each of the following molecules...Ch. 5 - Indicate whether each of the following molecules...Ch. 5 - Prob. 5.83EPCh. 5 - Prob. 5.84EPCh. 5 - Indicate which molecule in each of the following...Ch. 5 - Indicate which molecule in each of the following...Ch. 5 - Successive substitution of F atoms for H atoms in...Ch. 5 - Successive substitution of F atoms for H atoms in...Ch. 5 - Prob. 5.89EPCh. 5 - Indicate whether or not each of the following...Ch. 5 - Prob. 5.91EPCh. 5 - Name the following binary molecular compounds? a....Ch. 5 - Prob. 5.93EPCh. 5 - Prob. 5.94EPCh. 5 - Prob. 5.95EPCh. 5 - Prob. 5.96EPCh. 5 - Prob. 5.97EPCh. 5 - Prob. 5.98EPCh. 5 - Write chemical formulas for the following binary...Ch. 5 - Write chemical formulas for the following binary...Ch. 5 - Prob. 5.101EPCh. 5 - Prob. 5.102EPCh. 5 - The compound whose molecles contain one atom of C...Ch. 5 - Prob. 5.104EPCh. 5 - Prob. 5.105EPCh. 5 - The correct name for the compound K2SO4 is not...Ch. 5 - Prob. 5.107EPCh. 5 - Prob. 5.108EP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Starting from bromoethane, how could you prepare the following compounds: a. Ethanol. b. Acetaldehyde f. Acetone. e. 2-Propanol i. Acetoacetic ester. d. 2-Bromoacetic acid. c. Acetic acid g. Acetamide. j. Ethylmalonate k. Gama ketoacid. h. Ethyl magnesium bromide.arrow_forward- The pressure above a pure sample of solid Substance X at 60. °C is raised. At what pressure will the sample melt? Use the phase diagram of X below to find your answer. pressure (atm) 02 0.4 solid Hliquid gas 0 0 200 400 600 temperature (K) Note: your answer must be within 0.025 atm of the exact answer to be graded correct. ☐ atmarrow_forward15. What is the order of decreasing reactivity towards nucleophilic acyl substitution for the carboxylic acid derivatives? (most reactive first) 0 O H3C COC CH3 H₂C C N(CH3)2 H3C C OCH3 A. a. I, 11, 111, b. I, III, IV, II C. II, IV, III, I ° (CH3)2CH C OCH3 IV d. II, I, III, IV B. R COCR 0 0 0 13= RC NH2 RC OR RC CI === IV a. I, III, II, IV b. II, III, I, IV C. III, II, I, IV d. IV, I, III, IIarrow_forward
- Draw the formula of the product obtained by reacting D-Tallose with bromine water.arrow_forwardChoose the best reagent(s) for carrying out the following conversions from the list below. Place the letter corresponding to the best choice in the blank to the left of the conversion. a. KMnO4, H3O+ b. Tollens' Reagent [oxidizing reagent] C. NaBH4, ethanol d. 1. BH3 2. H3O+ e. 1. CH3MgBr, ether 2. H3O+ f. CrO3, H2SO4, H₂O g. 1. Mg, ether 2. CO2 3. H3O+ h. 1. NaCN 2. H2SO4, H2, heat i. O3, then Zn and HOAC j. CH₂I A. B. C. CH CH=CHCH2COOH Br CEN CH COOH + HOOCCH COOH COOH 010 CH3arrow_forwardDraw the structures for each of the intermediates in the boxes provided for the synthesis below. OCH3 Fe HO HNO (CHOO pynding H₂504 LHNO2 NACH-I Fa H₂O HCL HNO 180arrow_forward
- Provide structure(s) for the starting material(s), reagent(s) or the major organic product(s) of each of the following reactions or sequences of reactions. Show all relevant stereochemistry [three only] A. o 11 (CH3)CH — C— C ether (CH3)2CH-C-O-C-CH3 B. CH3 CHy CI Staf OH C. HC OCHS + H₂Oarrow_forwardConsider the reaction sequence below to answer the following questions: EtO Compound X 1. NaOEt, EtOH OEt Br CO₂Et NaOEt, EtOH Compound Z CO₂Et Compound Y A. Compound X, diethyl propanedioate, is more commonly known as a. ethyl acetoacetate b. acetoacetic ester C. oxalic ester d. malonic ester 3. Write the complete stepwise mechanism for the conversion of Compound X into Compound Y. Show all electron flow with arrows and draw all intermediate structures.arrow_forwardClassify each of the following nitrogen atoms in the following compounds as primary, secondary, tertiary, or quaternary [three only] CH3 HO-CHCHNHCH3 A. B. C. H&C CH3 D. HO phedrine CH2CHCH3 amphetamine NH₂ mepiquat chloride faxofenadine OH H&C CH CO₂Harrow_forward
- Draw the structure of the aldol self-condensation product for each of the following compounds. If a compound does not undergo aldol self-condensation, explain why it does not. A. B. CHICHCH₂OH CH3CHCH2CH CH3 CH3 C. CH 30 H3C-C-C-H CH3 questionsarrow_forward. A.Propose a synthesis for propylbenzene which avoids the problems of direct Friedel-Crafts alkylation. B. Consider the reaction below to answer the following questions. A B C NO2 Febr Brz D The Lewis acid catalyst in the reaction is: a. The nucleophile in the reaction is: b. C. d. This reaction proceeds Draw the structure of product D. (faster or slower) than benzene.arrow_forwardConsider the reaction below to answer the following questions. HOCH CHOH На A B C D H₂Oarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning

Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,

General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning

Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning

Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning