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Concept explainers
(a)
Interpretation:
The total number of electron dots that has to appear in Lewis structure for
Concept Introduction:
Lewis structure clearly depicts the bonding and nonbonding electrons in the atom. This is only partially useful for the molecule that contains one or more multiple bonds and when coordinate covalent bond is present in the molecule. For drawing Lewis structure a systematic procedure is followed. They are,
- The total number of valence electrons that is present in molecule is calculated by adding all the valence electrons of the atoms present in the molecule.
- The chemical symbols for the atoms that is present in the molecule is written in the order that they are bonded. After this a single covalent bond is placed between each atoms as two electrons.
- The nonbonding electrons are added to each atom that is bonded to the central atom so that it contains octet of electrons. For hydrogen alone the “octet” is only two electrons.
- The remaining electrons has to be placed on the central atom in the structure.
- If there is no octet of electrons present in the central atom, then use one or more pairs of nonbonding electrons that is bonded to the central atom to form double or triple bonds.
- The positive or negative charge that is present on the ion is adjusted by increasing or decreasing the number of electrons in the polyatomic ion.
(b)
Interpretation:
The total number of electron dots that has to appear in Lewis structure for
Concept Introduction:
Lewis structure clearly depicts the bonding and nonbonding electrons in the atom. This is only partially useful for the molecule that contains one or more multiple bonds and when coordinate covalent bond is present in the molecule. For drawing Lewis structure a systematic procedure is followed. They are,
- The total number of valence electrons that is present in molecule is calculated by adding all the valence electrons of the atoms present in the molecule.
- The chemical symbols for the atoms that is present in the molecule is written in the order that they are bonded. After this a single covalent bond is placed between each atoms as two electrons.
- The nonbonding electrons are added to each atom that is bonded to the central atom so that it contains octet of electrons. For hydrogen alone the “octet” is only two electrons.
- The remaining electrons has to be placed on the central atom in the structure.
- If there is no octet of electrons present in the central atom, then use one or more pairs of nonbonding electrons that is bonded to the central atom to form double or triple bonds.
- The positive or negative charge that is present on the ion is adjusted by increasing or decreasing the number of electrons in the polyatomic ion.
(c)
Interpretation:
The total number of electron dots that has to appear in Lewis structure for
Concept Introduction:
Lewis structure clearly depicts the bonding and nonbonding electrons in the atom. This is only partially useful for the molecule that contains one or more multiple bonds and when coordinate covalent bond is present in the molecule. For drawing Lewis structure a systematic procedure is followed. They are,
- The total number of valence electrons that is present in molecule is calculated by adding all the valence electrons of the atoms present in the molecule.
- The chemical symbols for the atoms that is present in the molecule is written in the order that they are bonded. After this a single covalent bond is placed between each atoms as two electrons.
- The nonbonding electrons are added to each atom that is bonded to the central atom so that it contains octet of electrons. For hydrogen alone the “octet” is only two electrons.
- The remaining electrons has to be placed on the central atom in the structure.
- If there is no octet of electrons present in the central atom, then use one or more pairs of nonbonding electrons that is bonded to the central atom to form double or triple bonds.
- The positive or negative charge that is present on the ion is adjusted by increasing or decreasing the number of electrons in the polyatomic ion.
(d)
Interpretation:
The total number of electron dots that has to appear in Lewis structure for
Concept Introduction:
Lewis structure clearly depicts the bonding and nonbonding electrons in the atom. This is only partially useful for the molecule that contains one or more multiple bonds and when coordinate covalent bond is present in the molecule. For drawing Lewis structure a systematic procedure is followed. They are,
- The total number of valence electrons that is present in molecule is calculated by adding all the valence electrons of the atoms present in the molecule.
- The chemical symbols for the atoms that is present in the molecule is written in the order that they are bonded. After this a single covalent bond is placed between each atoms as two electrons.
- The nonbonding electrons are added to each atom that is bonded to the central atom so that it contains octet of electrons. For hydrogen alone the “octet” is only two electrons.
- The remaining electrons has to be placed on the central atom in the structure.
- If there is no octet of electrons present in the central atom, then use one or more pairs of nonbonding electrons that is bonded to the central atom to form double or triple bonds.
- The positive or negative charge that is present on the ion is adjusted by increasing or decreasing the number of electrons in the polyatomic ion.
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Chapter 5 Solutions
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
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- Please help me figure out what the slope is and how to calculate the half life Using the data provided.arrow_forwardCurved arrows are used to illustrate the flow of electrons. Follow the curved arrows and draw the structure of the missing reactants, intermediates, or products in the following mechanism. Include all lone pairs. Ignore stereochemistry. Ignore inorganic byproducts. H Br2 (1 equiv) H- Select to Draw Starting Alkene Draw Major Product I I H2O 四: ⑦.. Q Draw Major Charged Intermediate Iarrow_forwardNH (aq)+CNO (aq) → CO(NH2)2(s) Experiment [NH4] (M) [CNO] (M) Initial rate (M/s) 1 0.014 0.02 0.002 23 0.028 0.02 0.008 0.014 0.01 0.001 Calculate the rate contant for this reaction using the data provided in the table.arrow_forward
- 2CIO2 + 20H-1 CIO31 + CIO2 + H2O Experiment [CIO2], M [OH-1], M 1 0.0500 0.100 23 2 0.100 0.100 3 0.100 0.0500 Initial Rate, M/s 0.0575 0.230 0.115 ... Given this date, calculate the overall order of this reaction.arrow_forward2 3 .(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I Experiment [1-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 0.000069 4 0.0025 0.0025 0.000140 Calculate the rate constant of this reaction using the table data.arrow_forward1 2 3 4 I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq) Experiment [I-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 Calculate the overall order of this reaction using the table data. 0.0025 0.000069 0.0025 0.000140arrow_forward
- H2O2(aq) +3 I¯(aq) +2 H+(aq) → 13(aq) +2 H₂O(l)· ••• Experiment [H2 O2]o (M) [I]o (M) [H+]。 (M) Initial rate (M/s) 1 0.15 0.15 0.05 0.00012 234 0.15 0.3 0.05 0.00024 0.3 0.15 0.05 0.00024 0.15 0.15 0.1 0.00048 Calculate the overall order of this reaction using the table data.arrow_forwardThe U. S. Environmental Protection Agency (EPA) sets limits on healthful levels of air pollutants. The maximum level that the EPA considers safe for lead air pollution is 1.5 μg/m³ Part A If your lungs were filled with air containing this level of lead, how many lead atoms would be in your lungs? (Assume a total lung volume of 5.40 L.) ΜΕ ΑΣΦ = 2.35 1013 ? atoms ! Check your rounding. Your final answer should be rounded to 2 significant figures in the last step. No credit lost. Try again.arrow_forwardY= - 0.039 (14.01) + 0.7949arrow_forward
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