Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 5.6, Problem 28ATS
Interpretation Introduction
Interpretation:
The stereoisomers should be drawn for the given organic molecules by using its structure.
Concept Introduction:
Stereoisomers: The molecule that have same molecular formula and sequence of bonded atoms, but different in the three-dimensional orientation of their in space.
Chiral: Chiral molecules contain at least one carbon atom with four non-identical substitutions (or) groups. This type of molecule is called a chiral center.
Diastereomers: This type of stereoisomers that ae not mirror images of one another and non-superimposable on one another. Molecule with two or more stereocenters it can be diastereomers.
Meso isomers: The molecule with multiple stereocenters that is superimposable on tit mirror images. Meso compounds are achiral that are multiple chiral center.
To Identify: The stereoisomers should be drawn for the given organic molecules.
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
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Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
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Aa
BCC
V
52 5
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Chapter 5 Solutions
Organic Chemistry
Ch. 5.1 - Prob. 1LTSCh. 5.1 - Prob. 1PTSCh. 5.2 - Prob. 2LTSCh. 5.2 - Prob. 5ATSCh. 5.2 - Prob. 3LTSCh. 5.3 - Prob. 4LTSCh. 5.3 - Prob. 10ATSCh. 5.3 - Prob. 11ATSCh. 5.4 - Prob. 5LTSCh. 5.4 - Prob. 12PTS
Ch. 5.4 - Prob. 13PTSCh. 5.4 - Prob. 14PTSCh. 5.4 - Prob. 15ATSCh. 5.4 - Prob. 16ATSCh. 5.4 - Prob. 6LTSCh. 5.4 - Prob. 17PTSCh. 5.4 - Prob. 18PTSCh. 5.4 - Prob. 19PTSCh. 5.4 - Prob. 20ATSCh. 5.5 - Prob. 7LTSCh. 5.5 - Prob. 21PTSCh. 5.5 - Prob. 22ATSCh. 5.6 - Prob. 23CCCh. 5.6 - Prob. 24CCCh. 5.6 - Prob. 25CCCh. 5.6 - Prob. 8LTSCh. 5.6 - Prob. 26PTSCh. 5.6 - Prob. 27ATSCh. 5.6 - Prob. 28ATSCh. 5.7 - Prob. 9LTSCh. 5.7 - Prob. 29PTSCh. 5.7 - Prob. 30ATSCh. 5.7 - Prob. 31ATSCh. 5 - Prob. 32PPCh. 5 - Prob. 33PPCh. 5 - Prob. 34PPCh. 5 - Prob. 35PPCh. 5 - Prob. 36PPCh. 5 - Prob. 37PPCh. 5 - Prob. 38PPCh. 5 - Prob. 39PPCh. 5 - Prob. 40PPCh. 5 - Prob. 41PPCh. 5 - Prob. 42PPCh. 5 - Prob. 43PPCh. 5 - Prob. 44PPCh. 5 - Prob. 45PPCh. 5 - Prob. 46PPCh. 5 - Prob. 47PPCh. 5 - Prob. 48PPCh. 5 - Prob. 49PPCh. 5 - Prob. 50PPCh. 5 - Prob. 51PPCh. 5 - Prob. 52PPCh. 5 - Prob. 53IPCh. 5 - Prob. 54IPCh. 5 - Prob. 55IPCh. 5 - Prob. 56IPCh. 5 - Prob. 57IPCh. 5 - Prob. 58IPCh. 5 - Prob. 59IPCh. 5 - Prob. 60IPCh. 5 - Prob. 61IPCh. 5 - Prob. 62IPCh. 5 - Prob. 63IPCh. 5 - Prob. 64IPCh. 5 - Prob. 65IP
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