Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
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Chapter 5, Problem 65IP
Interpretation Introduction
Interpretation:
To assign the configuration of each chiral center and draw possible stereoisomers of given molecules by using its structure.
The chiral center and configuration should be identified for the given molecules by using its structure.
Concept Introduction:
The single chiral atoms or similar structural feature in a compound causes that compound to have two possible structures which are non-superimposable, each a mirror image of the other.
The enantiomers are chiral molecules that are mirror images of one another, these type of molecules are non-superimposable on one another. This means that the molecules canot be placed on top of one another and give the same molecule. Further chiral molecules with one or more stereo centers it can be enantiomers.
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Draw the epoxide formed when the following alkene is treated with mCPBA. Click the "draw
structure" button to launch the drawing utility.
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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Chapter 5 Solutions
Organic Chemistry
Ch. 5.1 - Prob. 1LTSCh. 5.1 - Prob. 1PTSCh. 5.2 - Prob. 2LTSCh. 5.2 - Prob. 5ATSCh. 5.2 - Prob. 3LTSCh. 5.3 - Prob. 4LTSCh. 5.3 - Prob. 10ATSCh. 5.3 - Prob. 11ATSCh. 5.4 - Prob. 5LTSCh. 5.4 - Prob. 12PTS
Ch. 5.4 - Prob. 13PTSCh. 5.4 - Prob. 14PTSCh. 5.4 - Prob. 15ATSCh. 5.4 - Prob. 16ATSCh. 5.4 - Prob. 6LTSCh. 5.4 - Prob. 17PTSCh. 5.4 - Prob. 18PTSCh. 5.4 - Prob. 19PTSCh. 5.4 - Prob. 20ATSCh. 5.5 - Prob. 7LTSCh. 5.5 - Prob. 21PTSCh. 5.5 - Prob. 22ATSCh. 5.6 - Prob. 23CCCh. 5.6 - Prob. 24CCCh. 5.6 - Prob. 25CCCh. 5.6 - Prob. 8LTSCh. 5.6 - Prob. 26PTSCh. 5.6 - Prob. 27ATSCh. 5.6 - Prob. 28ATSCh. 5.7 - Prob. 9LTSCh. 5.7 - Prob. 29PTSCh. 5.7 - Prob. 30ATSCh. 5.7 - Prob. 31ATSCh. 5 - Prob. 32PPCh. 5 - Prob. 33PPCh. 5 - Prob. 34PPCh. 5 - Prob. 35PPCh. 5 - Prob. 36PPCh. 5 - Prob. 37PPCh. 5 - Prob. 38PPCh. 5 - Prob. 39PPCh. 5 - Prob. 40PPCh. 5 - Prob. 41PPCh. 5 - Prob. 42PPCh. 5 - Prob. 43PPCh. 5 - Prob. 44PPCh. 5 - Prob. 45PPCh. 5 - Prob. 46PPCh. 5 - Prob. 47PPCh. 5 - Prob. 48PPCh. 5 - Prob. 49PPCh. 5 - Prob. 50PPCh. 5 - Prob. 51PPCh. 5 - Prob. 52PPCh. 5 - Prob. 53IPCh. 5 - Prob. 54IPCh. 5 - Prob. 55IPCh. 5 - Prob. 56IPCh. 5 - Prob. 57IPCh. 5 - Prob. 58IPCh. 5 - Prob. 59IPCh. 5 - Prob. 60IPCh. 5 - Prob. 61IPCh. 5 - Prob. 62IPCh. 5 - Prob. 63IPCh. 5 - Prob. 64IPCh. 5 - Prob. 65IP
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