Concept explainers
(a)
Interpretation:
Movement of electrons should be indicated using curved arrows for the given reaction.
Concept introduction:
Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.
Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.
Curved arrows used to understand a reaction mechanism.
Curved arrows are drawn to show how the electrons move as new covalent bonds are formed existing covalent bonds are broken.
Each arrow represents the simultaneous movement of two electrons from a nucleophile towards an electrophile.
The tail of the arrow is positioned where the electrons are in the reactant; the tail always start at a lone pair of electron or at a bond.
The head of the arrow points to where these same electrons end up in the product; the arrow always points at an atom or a bond.
(b)
Interpretation:
Movement of electrons should be indicated using curved arrows for the given reaction.
Concept introduction:
Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.
Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.
Curved arrows used to understand a reaction mechanism.
Curved arrows are drawn to show how the electrons move as new covalent bonds are formed existing covalent bonds are broken.
Each arrow represents the simultaneous movement of two electrons from a nucleophile towards an electrophile.
The tail of the arrow is positioned where the electrons are in the reactant; the tail always starts at a lone pair of electron or at a bond.
The head of the arrow points to where these same electrons end up in the product; the arrow always points at an atom or a bond.
(b)
Interpretation:
Movement of electrons should be indicated using curved arrows for the given reaction.
Concept introduction:
Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.
Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.
Curved arrows used to understand a reaction mechanism.
Curved arrows are drawn to show how the electrons move as new covalent bonds are formed existing covalent bonds are broken.
Each arrow represents the simultaneous movement of two electrons from a nucleophile towards an electrophile.
The tail of the arrow is positioned where the electrons are in the reactant; the tail always starts at a lone pair of electron or at a bond.
The head of the arrow points to where these same electrons end up in the product; the arrow always points at an atom or a bond.
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Chapter 5 Solutions
EBK ORGANIC CHEMISTRY
- See attached file ?arrow_forwardAdd curved arrows to the reactants in this reaction. A double-barbed curved arrow is used to represent the movement of a pair of electrons. Draw curved arrows. Select Draw Rings More Erase | : 0 H-O: H OHarrow_forwarddraw the step one product and draw curved arrows to show the nucleophilic addition step.arrow_forward
- Draw the products for the following reactionarrow_forwardDraw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. LOCH3 LOCH3 HNO3 / CH3CO₂H O₂N • You do not have to consider stereochemistry. • Include all valence lone pairs in your answer. ● In cases where there is more than one answer, just draw one.arrow_forwardConsider this nucleophilic substitution reaction. 1. Highlight the electrophilic carbon in red, and highlight the leaving group in blue. Highlight the atom in the nucleophile that will attack the electrophilic center in green. Only atoms need to be highlighted and not the lone pairs or formal charges. 2. Draw the product(s) of the reaction. Include all lone pairs.arrow_forward
- Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction.arrow_forwardCurved arrows are used to illustrate the flow of electrons. Follow the arrows and draw the intermediate and product in this reaction. Include all lone pairs and charges as appropriate. Ignore stereochemistry. Ignore inorganic byproducts.arrow_forwardComplete this mechanism for an acid-base reaction by adding curved arrows. H :0: H H Add/Remove step H H HO O olo Ararrow_forward
- a) draw the structure of the tetrahedral intermediate INITIALLT-FORMED in the reaction shown. b) Draw the structures of the organic products of the acyl transfer reaction.arrow_forwardConsider the reaction between 2-methyl-2-butanol and HBr, shown below. но HBr Brarrow_forwardHow might nucleophilic catalysis work?Draw out a possible mechanism.arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage LearningEBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENT