EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Chapter 5.6, Problem 20P
a. Calculate the percentage of isopropylcylohexane molecules that have the isopropyl substituent in an equatorial position at equilibrium. (Its ∆G° value at 25°C is –2.1 kcal/mol.)
b. Why is the percentage of molecules with the substituent in an equatorial position greater for isopropylcyklohexane than for fluorocyclohexane?
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Add the following group of numbers using the correct number of significant figures for the
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The emf at 25°C of the cell: Pt l H2(g) l dis X:KCl (sat) l Hg2Cl2(s) l Hg l Pt was 612 mV. When solution X was replaced by normal phosphate buffer solution with a pH of 6.86, the emf was 741 mV. Calculate the pH of solution X.
Indicate how to calculate the potential E of the reaction Hg2Cl2(s) + 2e ⇄ 2Hg + 2Cl- as a function of the concentration of Cl- ions. Data: the solubility product of Hg2Cl2.
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