EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Textbook Question
Chapter 5.9, Problem 25P
How many different
a. butane?
b. 3-methylpentaoe?
c. hexane?
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1. In dash-wedge-line structure, the dashes represent the: *
A. bonds in the plane of the page.
B. bonds away from observer.
C. bonds towards observer.
D. bonds in the plane of the paper.
2. Which of the following is an ACYCLIC SATURATED hydrocarbon? *
A. 1-Ethyl-3-methylcyclopentane
B. 3-Ethyl-3-methylpentane
C. 1,3,5,7-Octatetraene
D. 5-Methyl-1,3-cyclopentadiene
3. Which of the following is a CYCLIC SATURATED hydrocarbon? *
A. 3-Ethyl-4-methylcyclohexene
B. 3,5-Diethyloctane
C. 2,2-Dimethyl-3-heptyne
D. 3-Butyl-1,1-dimethyl-5-propylcyclohexane
1.
a. Draw the structures of the two isomers of dibromoethane. Name them by the IUPAC system.
b. Draw out the structures of the two isomers of iodopropane. Name them by the IUPAC system.
c. Draw the structures of the three isomers of dichloroethene. Name each one by the IUPAC system, indicating stereochemistry where relevant.
Which among the following compounds has the most electronegative carbon in structure?
a. benzaldehyde
b. benzene
c. cyclobutane
d. butyne
The radical substitution reaction is primarily observed in the following reactions. Which reaction is it?
a. Oxidation of but-2-ene
b. Boiling of hex-3-ene
c. Chlorination of butane
d. Combustion of methane
Which among the following statements is FALSE about alkanes and cycloalkanes?
a. all alkanes produce CO2 and water vapor upon complete combustion
b. alkanes undergo substitution reactions
c. the empirical formula of all alkanes is CnH2n+2
d. cyclic alkanes exhibit bond strain in the sp#-sp# sigma bonds
Chapter 5 Solutions
EBK ORGANIC CHEMISTRY
Ch. 5.1 - What is the molecular formula for each of the...Ch. 5.1 - Prob. 4PCh. 5.1 - Determine the degree of unsaturation and then draw...Ch. 5.1 - Prob. 6PCh. 5.2 - What is each compounds systematic name?Ch. 5.2 - Prob. 8PCh. 5.2 - Draw the structure for each of the following: a....Ch. 5.3 - How many carbons are in the planar double-bond...Ch. 5.3 - Prob. 12PCh. 5.5 - Prob. 13P
Ch. 5.5 - Prob. 14PCh. 5.5 - Prob. 16PCh. 5.5 - Prob. 17PCh. 5.6 - a. Which of the monosubstituted cyclohexanes in...Ch. 5.6 - a. Calculate the percentage of isopropylcylohexane...Ch. 5.6 - a. for which reaction in each set will S be more...Ch. 5.6 - a. For a reaction with H = 12 kcal/ mol and S =...Ch. 5.8 - Prob. 23PCh. 5.9 - Prob. 24PCh. 5.9 - How many different alkenes can be hydrogenated to...Ch. 5.9 - The same alkane is obtained from the catalytic...Ch. 5.9 - Prob. 27PCh. 5.9 - Rank the following compounds from most stable to...Ch. 5.10 - Prob. 29PCh. 5.10 - Prob. 30PCh. 5.11 - The rate constant for a reaction can be increased...Ch. 5.11 - Prob. 33PCh. 5.11 - a. Which reaction has a greater equilibrium...Ch. 5.12 - Draw a reaction coordinate diagram for a two-step...Ch. 5.12 - a. Which step in the reaction coordinate diagram...Ch. 5.12 - Draw a reaction coordinate diagram for the...Ch. 5.13 - Prob. 38PCh. 5 - What is each compounds systematic name?Ch. 5 - Prob. 40PCh. 5 - Draw the structure of a hydrocarbon that has six...Ch. 5 - Draw the condensed structure for each of the...Ch. 5 - Prob. 43PCh. 5 - Prob. 44PCh. 5 - Prob. 45PCh. 5 - Name the following:Ch. 5 - Prob. 47PCh. 5 - Prob. 48PCh. 5 - Prob. 49PCh. 5 - In a reaction in which reactant A is in...Ch. 5 - Which bond is stronger? Briefly explain why.Ch. 5 - Prob. 52PCh. 5 - Prob. 53PCh. 5 - By following the curved red arrows, draw the...Ch. 5 - Prob. 55PCh. 5 - Prob. 56PCh. 5 - Draw structures for the following: a....Ch. 5 - Prob. 58PCh. 5 - a. Which of the following reactions has the larger...Ch. 5 - Prob. 60PCh. 5 - a. What is the equilibrium constant for a reaction...Ch. 5 - Prob. 62PCh. 5 - Prob. 63PCh. 5 - Given that the free energy of the twist-boat...Ch. 5 - Prob. 65PCh. 5 - Prob. 1PCh. 5 - Prob. 2PCh. 5 - Prob. 3PCh. 5 - Prob. 4PCh. 5 - Prob. 5PCh. 5 - Prob. 6PCh. 5 - Draw curved arrows to show the movement of the...Ch. 5 - Prob. 8PCh. 5 - Prob. 9PCh. 5 - Prob. 10P
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- a. Draw each the chemical structure the Folloung OF 2,2,4-TRIMethylpentane b. cycloheptene Forarrow_forwardWhat is the product of a reaction between 1-bromoethane with ammonia? A. acetonitrile B. ethanamine C. ethyl ethanoate D. ethanolarrow_forwardDraw the structure corresponding to each IUPAC name. a.3-ethyl-2-methylhexane b. sec-butylcyclopentane c.4-isopropyl-2,4,5-trimethylundecane d.cyclobutylcycloheptane e.3-ethyl-1,1-dimethylcyclohexane f. 4-butyl-1,1-diethylcyclooctane g.6-isopropyl-2,3-dimethyldodecane h. 2,2,6,6,7-pentamethyloctane i. cis-1-ethyl-3-methylcyclopentane j. trans-1-tert-butyl-4-ethylcyclohexanearrow_forward
- Which is not the structure of alkene.arrow_forward2. Draw the following molecules 2-methyl-4-propyloctane a. b. 2-heptanone c. Methylbutyletherarrow_forwardQ1. Name each of the following structures by the IUPAC system? B. W C. Q2. Write the structural formula for the following? A. 1,4-dichloro-2-pentene B. 2-bromo-1,3-pentadiene C. vinyl cyclohexane Q3. Which of the following compounds can exist as cis- trans isomers? Draw their structures? A.. pentene B. 2-methyl-2-pentene Q3. Writ an equitation for the A. Reaction for bromine at room temperature 1. Propene B. The acid catalyzed addition of water to 1. 3-hexene Q4. For the addition of HBr to 3-methyl-1-butene, two products were observed. Show the reaction mechanism to explain the formation of both products. HBr - 3-methyl-1-butene major minorarrow_forward
- Name each monosubstituted benzene. CH3 Br a. b. C.arrow_forward1. Write the structural formulae and names of at least 3 isomers of heptane. Label each with each nomenclature.arrow_forward12. Write structural formulas for the following alkene names. a. hept-2-ene b. hex-2-ene 6,7-dimethyloct-1-ene d. 2,4-dimethyloct-4-ene с. 3-ethylnon-2-ene е.arrow_forward
- 1) A carbene is which of the following? a. A carbon that is part of an alkene functional group b. A carbocation formed from an alkene functional group c. Another name for an alkene functional group d. An octet deficient carbon with a lone pair e. An azeotrope of diazomethane and waterarrow_forward1. Name and describe 2 chemical tests to differentiate: а. n-hexane from ethene b. acetylene from hex-1-ene Describe reactivity of alkenes 2.arrow_forward16. Draw condensed structures corresponding to each name below. a. 2-methyl-1,3-butadiene b. (2Z,4Z)-hexadienearrow_forward
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