Most stable alkenes has to be identified. Concept introduction: The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation ( Δ H 0 ) . The most stable alkene has the smallest heat of hydrogenation. The stability of an alkene increases as the number of alkyl substituents bonded to its s p 2 carbon increases. The stability of an alkene increases as the number of hydrogen bonded to its s p 2 carbon decreases.

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Answer 1

Question

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation:

Most stable alkenes has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

(b)

Interpretation Introduction

Interpretation:

Least stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation:

Most stable alkenes has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

(b)

Interpretation Introduction

Interpretation:

Least stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

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Answer 3

Question

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation:

Most stable alkenes has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

(b)

Interpretation Introduction

Interpretation:

Least stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

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Answer 4

Question

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation:

Most stable alkenes has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

(b)

Interpretation Introduction

Interpretation:

Least stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

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Answer 5

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation:

Most stable alkenes has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

(b)

Interpretation Introduction

Interpretation:

Least stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 6

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation:

Most stable alkenes has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 7

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation:

Most stable alkenes has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Least stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Least stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 5.1 - What is the molecular formula for each of the...Ch. 5.1 - Prob. 4P Ch. 5.1 - Determine the degree of unsaturation and then draw...Ch. 5.1 - Prob. 6P Ch. 5.2 - What is each compounds systematic name?Ch. 5.2 - Prob. 8P Ch. 5.2 - Draw the structure for each of the following: a....Ch. 5.3 - How many carbons are in the planar double-bond...Ch. 5.3 - Prob. 12P Ch. 5.5 - Prob. 13P

Solution Summary: The author explains that the most stable alkenes have to be identified.

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Chapter 5 Solutions