Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter 5, Problem 6CTQ
Interpretation Introduction

Interpretation: The synonym of delocalization in organic chemistry should be determined.

Concept introduction: Lewis structure is a representation of molecules in which dots are shown to represent unshared electrons and lines are shown to represent bonds. These lines and dots represent distribution of electrons in the molecule.

When one single structure is unable to describe all the properties of a single-molecule, a phenomenon called resonance comes into play. This arises when two or more than two Lewis structures are possible for one molecule. All such structures are called resonating structures and have same placement of atoms in them but these have different locations of bond pairs and lone pairs. The resonating structures are inter-convertible with each other. The resultant of all the resonating or contributing structures is called the resonance hybrid.

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2. Provide a complete retrosynthetic analysis and a complete forward synthetic scheme to make the following target molecule from the given starting material. You may use any other reagents necessary. Br
146. Use the following data for NH3(g) at 273 K to determine B2p (T) at 273 K. P (bar) 0.10 0.20 0.30 0.40 0.50 0.60 (Z -1)/10-4 1.519 3.038 4.557 6.071 7.583 9.002 0.70 10.551
110. Compare the pressures given by (a) the ideal gas law, (b) the van der Waals equation, and (c) the Redlic-Kwong equation for propane at 400 K and p = 10.62 mol dm³. The van der Waals parameters for propane are a = 9.3919 dm6 bar mol-2 and b = 0.090494 dm³ mol−1. The Redlich-Kwong parameters are A = 183.02 dm bar mol-2 and B = 0.062723 dm³ mol-1. The experimental value is 400 bar.

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