Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter 5, Problem 7CTQ

On which do you expect to have a more intense and concentrated “hotspot” of negative charge: methoxideion or bicarbonate ion?

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Provide the correct IUPAC name for HBrO₂(aq).     (I) (II) (III) (IV) tri- hepta- penta- mono- octa- di- hexa- tetra- hypobromic hypobromous hydrobromic bromic hydrobromous perbromic perbromous bromous hydrate acid Delete
Answer Q45, 46, 47
The “free-base” form of cocaine (C17H21NO4) and its protonatedhydrochloride form (C17H22ClNO4) are shownbelow; the free-base form can be converted to the hydrochlorideform with one equivalent of HCl. For clarity, notall the carbon and hydrogen atoms are shown; each vertexrepresents a carbon atom with the appropriate number ofhydrogen atoms so that each carbon makes four bonds toother atoms.(a) One of these forms of cocaine is relatively water-soluble:which form, the free base or the hydrochloride?(b) One of these forms of cocaine is relatively insoluble inwater: which form, the free base or the hydrochloride? (c) The free-base form of cocaine has a solubility of 1.00 g in6.70 mL ethanol (CH3CH2OH). Calculate the molarityof a saturated solution of the free-base form of cocaine inethanol.(d) The hydrochloride form of cocaine has a solubility of1.00 g in 0.400 mL water. Calculate the molarity of a saturatedsolution of the hydrochloride form of cocaine inwater.(e) How many mL of a…

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