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Urea
Ammonia gas at 223°C and 90. atm flows into a reactorat a rate of 500. L/min. Carbon dioxide at 223°C and45 atm flows into the reactor at a rate of 600. L/min.What mass of urea is produced per minute by this reactionassuming 100% yield?
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Chapter 5 Solutions
Chemical Principles
- Urea (H2NCONH2) is used extensively as a nitrogen source in fertilizers. It is produced commercially from the reaction of ammonia and carbon dioxide: 2NH3(g)+CO2(g)PressureHeatH2NCONH2(s)+H2O(g) Ammonia gas at 223C and 90. atm flows into a reactor at a rate of 500. L/min. Carbon dioxide at 223C and 45 atm flows into the reactor at a rate of 600. L/min. What mass of urea is produced per minute by this reaction assuming 100% yield?arrow_forward97 Homes in rural areas where natural gas service is not available often rely on propane to fuel kitchen ranges. The propane is stored as a liquid, and the gas to be burned is produced as the liquid evaporates. Suppose an architect has hired you to consult on the choice of a propane tank for such a new home. The propane gas consumed in 1.0 hour by a typical range burner at high power would occupy roughly 165 L at 25°C and 1.0 atm, and the range chosen by the client will have six burners. If the tank under consideration holds 500.0 gallons of liquid propane, what is the minimum number of hours it would take for the range to consume an entire tankful of propane? The density of liquid propane is 0.5077 kg/L.arrow_forwardRaoul Pictet, the Swiss physicist who first liquefied oxygen, attempted to liquefy hydrogen. He heated potassium formate, KCHO2, with KOH in a closed 2.50-Lvessel. KCHO2(s)+KOH(s)K2CO3(s)+H2(g) If 75.0 g of potassium formate reacts in a 2.50-L vessel, which was initially evacuated, what pressure of hydrogen will be attained when the temperature is finally cooled to 25C? Use the preceding chemical equation and ignore the volume of solid product.arrow_forward
- Butyl mercaptan, C4H9SH, has a very bad odor and is among the compounds added to natural gas to help detect a leak of otherwise odorless natural gas. In an experiment, you burn 95.0 mg of C4H9SH and collect the product gases (SO2, CO2, and H2O) in a 5.25-L flask at 25 C. What is the total gas pressure in the flask, and what is the partial pressure of each of the product gases?arrow_forwardYou have an equimolar mixture of the gases SO2 and O2, along with some He, in a container fitted with a piston. The density of this mixture at STP is 1.924 g/L. Assume ideal behavior and constant temperature and pressure. a. What is the mole fraction of He in the original mixture? b. The SO2 and O2 react to completion to form SO3. What is the density of the gas mixture after the reaction is complete?arrow_forwardIn the Mthode Champenoise, grape juice is fermented in a wine bottle to produce sparkling wine. The reaction is C6H12O6(aq)2C2H5OH(aq)+2CO2(g) Fermentation of 750. mL grape juice (density = 1.0 g/cm3) is allowed to take place in a bottle with a total volume of 825 mL until 12% by volume is ethanol (C2H5OH). Assuming that the CO2 is insoluble in H2O (actually, a wrong assumption), what would be the pressure of CO2 inside the wine bottle at 25C? (The density of ethanol is 0.79 g/cm3.)arrow_forward
- Helium gas, He, at 22C and 1.00 atm occupied a vessel whose volume was 2.54 L. What volume would this gas occupy if it were cooled to liquid-nitrogen temperature (197C)?arrow_forwardLiquid oxygen was first prepared by heating potassium chlorate, KClO3, in a closed vessel to obtain oxygen at high pressure. The oxygen was cooled until it liquefied. 2KClO3(s)2KCl(s)+3O2(g) If 171 g of potassium chlorate reacts in a 2.70-L vessel, which was initially evacuated, what pressure of oxygen will be attained when the temperature is finally cooled to 25C? Use the preceding chemical equation and ignore the volume of solid product.arrow_forward5-114 Carbon dioxide gas, saturated with water vapor, can be produced by the addition of aqueous acid to calcium carbonate based on the following balanced net ionic equation: (a) How many moles of wet CO (g), collected at 60.°C and 774 torr total pressure, are produced by the complete reaction of 10.0 g of CaCO3 with excess acid? (b) What volume does this wet CO2 occupy? (c) What volume would the CO2 occupy at 774 torr if a desiccant (a chemical drying agent) were added to remove the water? The vapor pressure of water at 60.°C is 149.4 mm Hg.arrow_forward
- In a typical automobile engine, a gasoline vapor-air mixture is compressed and ignited in the cylinders of the engine. This results in a combustion reaction that produces mainly carbon dioxide and water vapor. For simplicity, assume that the fuel is C8H18 and has a density of 0.760 g/mL. (a) Calculate the partial pressures of N2 and 02 in the air before it goes into the cylinder; assume the atmospheric pressure is 734 mmHg. (b) Consider the case where the air, without any fuel added, is compressed in the cylinder to seven times atmospheric pressure, the compression ratio of many modem automobile engines. Calculate the partial pressures of N2 and O2 at this pressure. (c) Now consider the case where 0.050 mL gasoline is added to the air in the cylinder just before compression and completely vaporized. Assume that the volume of the cylinder is 485 mL and the temperature is 150C. Calculate the partial pressure of the gasoline vapor. (d) Calculate the amount (mol) of oxygen required to bum the gasoline in part (c) completely to CO2 and H2O. (e) The combustion reaction in the cylinder creates temperatures in excess of 1200K. Due to the high temperature, some of the nitrogen and oxygen in the air reacts to form nitrogen monoxide. If 10% of the nitrogen is converted to NO, calculate the mass (g) of NO produced by this combustion. (f) Hot-rod cars use another oxide of nitrogen, dinitrogen monoxide, to create an extra burst in power. When such a power boost is needed, dinitrogen monoxide gas is injected into the cylinders where it reacts with oxygen to form NO. Calculate the mass of dinitrogen monoxide that would have to be injected to form the same quantity of NO as produced in part (e). Assume that sufficient oxygen is present to do so.arrow_forwardAcetone peroxide, C9H18O6(s), is a powerful but highly unstable explosive that does not contain nitrogen. It can pass undetected through scanners designed to detect the presence of nitrogen in explosives like TNT (trinitrotoluene, C7H5N3O6), or ammonium nitrate. (a) Write a balanced equation for the combustion (burning in oxygen) of acetone peroxide producing steam and carbon dioxide. (b) What pressure is generated in a 2.00-L bottle when 5.00 g of acetone peroxide is ignited to 555C and burned in air? Assume 100% combustion.arrow_forwardCalculate the densities (in g/L) of the following gases at 78F and 13.6 psi. (a) xenon (b) methane (c) acetylene, C2H2arrow_forward
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