
Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question
Chapter 5, Problem 127AE
Interpretation Introduction
Interpretation:
The partial pressure of each gas should be calculated along with the total pressure after all the stopcocks are opened.
Concept Introduction:
Boyle's Law gives the relationship between Pressure (P) and Volume (V).
According to Boyle's Law, the volume of gas changes inversely with the pressure of the gas if temperature and amount of a gas are constant.
PV = constant
The pressure of a gas decreases with increase in volume; volume of a gas decreases with increase in pressure
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5 (a). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 6
5 (b). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 7
6. Are there any differences between the spectra you obtained
in Beyond Labz and the predicted spectra? If so, what were
the differences?
<
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Chapter 5 Solutions
Chemical Principles
Ch. 5 - Consider the following apparatus: a test tube...Ch. 5 - Prob. 2DQCh. 5 - Prob. 3DQCh. 5 - Prob. 4DQCh. 5 - Prob. 5DQCh. 5 - Prob. 6DQCh. 5 - Prob. 7DQCh. 5 - Prob. 8DQCh. 5 - Prob. 9DQCh. 5 - Prob. 10DQ
Ch. 5 - Prob. 11DQCh. 5 - Prob. 12DQCh. 5 - Prob. 13DQCh. 5 - Prob. 14DQCh. 5 - Prob. 15DQCh. 5 - Prob. 16DQCh. 5 - Prob. 17DQCh. 5 - For each of the quantities (af) listed below,...Ch. 5 - Prob. 19DQCh. 5 - Prob. 20DQCh. 5 - A sealed-tube manometer as shown below can be...Ch. 5 - A diagram for an open-tube manometer is shown...Ch. 5 - Prob. 23ECh. 5 - Prob. 24ECh. 5 - A gauge on a compressed gas cylinder reads 2200...Ch. 5 - Prob. 26ECh. 5 - Prob. 27ECh. 5 - Prob. 28ECh. 5 - Prob. 29ECh. 5 - Prob. 30ECh. 5 - A mixture of 1.00 g H2 and 1.00 g He is placed in...Ch. 5 - Prob. 32ECh. 5 - Prob. 33ECh. 5 - Prob. 34ECh. 5 - A piece of solid carbon dioxide, with a mass of...Ch. 5 - Prob. 36ECh. 5 - Suppose two 200.0-L tanks are to be filled...Ch. 5 - Prob. 38ECh. 5 - Prob. 39ECh. 5 - Prob. 40ECh. 5 - Prob. 41ECh. 5 - Prob. 42ECh. 5 - Prob. 43ECh. 5 - Prob. 44ECh. 5 - Prob. 45ECh. 5 - A sample of nitrogen gas was collected over water...Ch. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - A 1.00-L gas sample at 100.°C and 600. torr...Ch. 5 - Prob. 51ECh. 5 - Given that a sample of air is made up of nitrogen,...Ch. 5 - Prob. 53ECh. 5 - Prob. 54ECh. 5 - A compound contains only nitrogen and hydrogen and...Ch. 5 - A compound has the empirical formula CHCl. A...Ch. 5 - One of the chemical controversies of the...Ch. 5 - Discrepancies in the experimental values of the...Ch. 5 - A sample of methane (CH4) gas contains a small...Ch. 5 - Prob. 60ECh. 5 - Prob. 61ECh. 5 - Urea (H2NCONH2) is used extensively as a...Ch. 5 - Methanol (CH3OH) can be produced by the...Ch. 5 - Consider the reaction between 50.0 mL of liquid...Ch. 5 - Some very effective rocket fuels are composed of...Ch. 5 - Air bags are activated when a severe impact causes...Ch. 5 - Prob. 67ECh. 5 - Prob. 68ECh. 5 - Prob. 69ECh. 5 - Xenon and fluorine will react to form binary...Ch. 5 - The nitrogen content of organic compounds can be...Ch. 5 - Prob. 72ECh. 5 - Prob. 73ECh. 5 - Consider the following balanced equation in which...Ch. 5 - Prob. 75ECh. 5 - Prob. 76ECh. 5 - Prob. 77ECh. 5 - Prob. 78ECh. 5 - Prob. 79ECh. 5 - Prob. 80ECh. 5 - Calculate the average kinetic energies of the...Ch. 5 - Prob. 82ECh. 5 - Prob. 83ECh. 5 - Prob. 84ECh. 5 - Prob. 85ECh. 5 - Prob. 86ECh. 5 - Prob. 87ECh. 5 - One way of separating oxygen isotopes is by...Ch. 5 - A compound contains only C, H, and N. It is 58.51%...Ch. 5 - Prob. 90ECh. 5 - Prob. 91ECh. 5 - Prob. 92ECh. 5 - Why do real gases not always behave ideally?...Ch. 5 - Prob. 94ECh. 5 - Prob. 95ECh. 5 - Without looking at tables of values, which of the...Ch. 5 - Prob. 97ECh. 5 - Prob. 98ECh. 5 - Prob. 99ECh. 5 - Prob. 100ECh. 5 - Prob. 101ECh. 5 - Prob. 102ECh. 5 - Consider separate 1.0-L samples of O2(g) and...Ch. 5 - Consider separate 1.00-L samples of Ar(g), both...Ch. 5 - Calculate the intermolecular collision frequency...Ch. 5 - Prob. 106ECh. 5 - Prob. 107ECh. 5 - Prob. 108ECh. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Prob. 111ECh. 5 - Prob. 112AECh. 5 - Prob. 113AECh. 5 - Prob. 114AECh. 5 - Prob. 115AECh. 5 - Prob. 116AECh. 5 - Prob. 117AECh. 5 - Prob. 118AECh. 5 - A 2.747-g sample of manganese metal is reacted...Ch. 5 - Prob. 120AECh. 5 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2...Ch. 5 - Prob. 122AECh. 5 - Prob. 123AECh. 5 - Prob. 124AECh. 5 - Prob. 125AECh. 5 - Prob. 126AECh. 5 - Prob. 127AECh. 5 - Prob. 128AECh. 5 - Prob. 129AECh. 5 - Prob. 130AECh. 5 - Prob. 131AECh. 5 - Prob. 132AECh. 5 - Prob. 133AECh. 5 - Prob. 134AECh. 5 - Prob. 135AECh. 5 - Prob. 136AECh. 5 - Prob. 137AECh. 5 - Prob. 138AECh. 5 - Prob. 139AECh. 5 - Prob. 140AECh. 5 - Prob. 141AECh. 5 - Prob. 142AECh. 5 - Prob. 143AECh. 5 - Prob. 144AECh. 5 - Prob. 145AECh. 5 - Prob. 146CPCh. 5 - A 16.0-g sample of methane (CH4) reacts with 64.0...Ch. 5 - You have two samples of helium gas at the same...Ch. 5 - Prob. 149CPCh. 5 - Prob. 150CPCh. 5 - Prob. 151CPCh. 5 - Prob. 152CPCh. 5 - The density of a pure gaseous compound was...Ch. 5 - Prob. 154CPCh. 5 - The most probable velocity ump is the velocity...Ch. 5 - Derive Dalton’s law of partial pressures from the...Ch. 5 - One of the assumptions of the kinetic molecular...Ch. 5 - Prob. 158CPCh. 5 - A steel cylinder contains 5.00 moles of graphite...Ch. 5 - Prob. 160CPCh. 5 - Prob. 161CPCh. 5 - Prob. 162CPCh. 5 - Calculate the number of stages needed to change...Ch. 5 - Prob. 164CPCh. 5 - You have a helium balloon at 1.00 atm and 25°C....Ch. 5 - Prob. 166CPCh. 5 - Prob. 167MP
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