Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 5, Problem 40QAP
Acetone peroxide, C9H18O6(s), is a powerful but highly unstable explosive that does not contain nitrogen. It can pass undetected through scanners designed to detect the presence of nitrogen in explosives like TNT (trinitrotoluene, C7H5N3O6), or ammonium nitrate.
(a) Write a balanced equation for the combustion (burning in oxygen) of acetone peroxide producing steam and carbon dioxide.
(b) What pressure is generated in a 2.00-L bottle when 5.00 g of acetone peroxide is ignited to 555°C and burned in air? Assume 100% combustion.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Natural gas consists primarily of methane, CH4(g).(a) Write a balanced chemical equation for the completecombustion of methane to produce CO2(g) as the onlycarbon-containing product. (b) Write a balanced chemicalequation for the incomplete combustion of methaneto produce CO(g) as the only carbon-containing product.(c) At 25 °C and 1.0 atm pressure, what is the minimumquantity of dry air needed to combust 1.0 L of CH4(g) completelyto CO2(g)?
Hydrogen peroxide, H2O2, is a strong oxidizingagent. It is used as an antiseptic in a 3.0%aqueous solution. Some chlorine-free bleachescontain 6.0% hydrogen peroxide.(a) Write the balanced chemical equation for theformation of one mole of H2O2(l).
(b) Using the following equations, determine theenthalpy of formation of H2O2.(1) 2H2O2() → 2H2O() + O2(g) ∆H˚ = −196 kJ(2) H2(g) + 12 O2(g) → H2O() ∆H˚ = −286 kJ
(a) The atomic weight of carbon is 12, hydrogen is 1 and oxygen is 16, and the
formula for the combustion of methane (CH4) is given by :
CH4 + 2 O2 –→ CO2 + 2 H2O + energy
A mole of methane releases 810 KJ of energy on burning.
Calculate the weight of carbon dioxide produced by burning 5kg of methane.
Identify an alternative gas for combustion that produces less carbon dioxide
than methane and state how it is generated.
Chapter 5 Solutions
Chemistry: Principles and Reactions
Ch. 5 - Prob. 1QAPCh. 5 - A 6.00-ft cylinder has a radius of 26 in. It...Ch. 5 - Prob. 3QAPCh. 5 - Prob. 4QAPCh. 5 - A cylinder with a movable piston records a volume...Ch. 5 - A tank is filled with gas to a pressure of 875 mm...Ch. 5 - A sample of CO2 gas at 22C and 1.00 atm has a...Ch. 5 - A sample of nitrogen gas has a pressure of 1.22...Ch. 5 - Prob. 9QAPCh. 5 - A tire is inflated to a gauge pressure of 28.0 psi...
Ch. 5 - Prob. 11QAPCh. 5 - A sealed tank at room temperature, 25C, has 22.0 g...Ch. 5 - A balloon filled with helium hasa volume of...Ch. 5 - Prob. 14QAPCh. 5 - Prob. 15QAPCh. 5 - Prob. 16QAPCh. 5 - A piece of dry ice (CO2(s)) has a mass of 22.50 g....Ch. 5 - A four-liter tank is filled with propane gas,...Ch. 5 - Prob. 19QAPCh. 5 - Prob. 20QAPCh. 5 - Calculate the densities (in g/L) of the following...Ch. 5 - Calculate the densities (in grams per liter) of...Ch. 5 - Helium-filled balloons rise in the air because the...Ch. 5 - Space probes to Mars have shown that its...Ch. 5 - Cyclopropane mixed in the proper ratio with oxygen...Ch. 5 - Phosgene is a highly toxic gas made up of carbon,...Ch. 5 - The gas in the discharge cell of a laser contains...Ch. 5 - Exhaled air contains 74.5% N2, 15.7% O2, 3.6% CO2,...Ch. 5 - A 1.58-g sample of C2H3X3(g) has a volume of 297...Ch. 5 - A 0.750-g sample of the gas PX3 is in a sealed...Ch. 5 - Nitrogen oxide is a pollutant commonly found in...Ch. 5 - Nitrogen trifluoride gas reacts with steam to...Ch. 5 - Dichlorine oxide is used as bactericide to purify...Ch. 5 - Titanium(III) chloride is used in the manufacture...Ch. 5 - Nitric acid can be prepared by bubbling dinitrogen...Ch. 5 - Potassium peroxide is used to absorb the CO2...Ch. 5 - Hydrogen cyanide (HCN) is a poisonous gas. It can...Ch. 5 - When hydrogen peroxide decomposes, oxygen is...Ch. 5 - Ammonium nitrate can be used as an effective...Ch. 5 - Acetone peroxide, C9H18O6(s), is a powerful but...Ch. 5 - Prob. 41QAPCh. 5 - A certain laser uses a gas mixture consisting of...Ch. 5 - A sample of a smoke stack emission was collected...Ch. 5 - Prob. 44QAPCh. 5 - Prob. 45QAPCh. 5 - Prob. 46QAPCh. 5 - Prob. 47QAPCh. 5 - Follow the instructions of Problem 47 for the...Ch. 5 - When acetylene, C2H2, is burned in oxygen, carbon...Ch. 5 - When ammonium nitrate decomposes at 722C,...Ch. 5 - Prob. 51QAPCh. 5 - Nitrogen gas can be obtained by decomposing...Ch. 5 - Prob. 53QAPCh. 5 - Prob. 54QAPCh. 5 - Prob. 55QAPCh. 5 - Prob. 56QAPCh. 5 - A gas effuses 1.55 times faster than propane...Ch. 5 - A gas effuses through an opening one-fifth as fast...Ch. 5 - Prob. 59QAPCh. 5 - Prob. 60QAPCh. 5 - At what temperature will a molecule of uranium...Ch. 5 - Calculate the average speed of a (a) chlorine...Ch. 5 - Prob. 63QAPCh. 5 - Prob. 64QAPCh. 5 - Prob. 65QAPCh. 5 - Prob. 66QAPCh. 5 - Prob. 67QAPCh. 5 - Prob. 68QAPCh. 5 - Prob. 69QAPCh. 5 - Given that 1.00 mol of neon and 1.00 mol of...Ch. 5 - An intermediate reaction used in the production of...Ch. 5 - Prob. 72QAPCh. 5 - Prob. 73QAPCh. 5 - Glycine is an amino acid made up of carbon,...Ch. 5 - Prob. 75QAPCh. 5 - The Lamborghini Aventador engine has a 12-cylinder...Ch. 5 - Prob. 77QAPCh. 5 - Prob. 78QAPCh. 5 - Prob. 79QAPCh. 5 - Prob. 80QAPCh. 5 - Prob. 81QAPCh. 5 - Prob. 82QAPCh. 5 - Prob. 83QAPCh. 5 - The graph below shows the distribution of...Ch. 5 - Consider the following sketch. Each square in bulb...Ch. 5 - The following figure shows three 1.00-L bulbs...Ch. 5 - Prob. 87QAPCh. 5 - Prob. 88QAPCh. 5 - Prob. 89QAPCh. 5 - Prob. 90QAPCh. 5 - Prob. 91QAPCh. 5 - A 0.2500-g sample of an Al-Zn alloy reacts with...Ch. 5 - Prob. 93QAPCh. 5 - A mixture in which the mole ratio of hydrogen to...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Use the appropriate tables to calculate H for (a) the reaction between copper(II) oxide and carbon monoxide to give copper metal and carbon dioxide. (b) the decomposition of one mole of methyl alcohol (CH3OH) to methane and oxygen gases.arrow_forwardA gaseous hydrocarbon reacts completely with oxygen gas to form carbon dioxide and water vapour. Given the following data, determine Hf for the hydrocarbon: Hreaction=2044.5KJ/molhydrocarbonHf(CO2)=393.5KJ/molHf(H2O)=242KJ/mol Density of CO2 and H2O product mixture at 1.00 atm, 200.c = 0.751g/L. The density of the hydrocarbon is less than the density of Kr at the same conditions.arrow_forwardCalcium carbide, CaC2, is manufactured by reducing lime with carbon at high temperature. (The carbide is used in turn to make acetylene, an industrially important organic chemical.) Is the reaction endothermic or exothermic?arrow_forward
- If nitric acid were sufficiently heated, it can be decomposed into dinitrogen pentoxide and water vapor: 2HNO3(l)N2O5(g)+H2O(g)Hrxn=+176kJ (a) Calculate the enthalpy change that accompanies the reaction of 1.00 kg HNO3 (). (b) Is heat absorbed or released during the course of the reaction?arrow_forwardHow does hydraulic fracturing differ from previously used techniques for the recovery of natural gas from the earth?arrow_forwardButane gas, C4H10, is sold to campers as bottled fuel. Its density at 25C and 1.00 atm is 2.38 g/L. What volume of butane gas at 25C and 1.00 atm is required to heat one gallon of water (d=1.00g/mL) from 25C to 98C ? The reaction for the combustion of butane (H f =125.6kJ/mol) is C4H10(g)+132 O2(g)4CO2(g)+5H2O(g)arrow_forward
- What possible uses exist for the natural gas liquids that are removed from natural gas during its processing?arrow_forwardWhich of the following quantities can be taken to be independent of temperature? independent of pressure? (a) H for a reaction (b) S for a reaction (c) G for a reaction (d) S for a substancearrow_forward62 Ammonium dinitramide (ADN), NH4N(NO2)2, was considered as a possible replacement for aluminium chloride as the oxidizer in the solid fuel booster rockets used to launch the space shuttle. When detonated by a spark, AND rapidly decomposes to produce a gaseous mixture of N2,O2, and H2O. (This is not a combustion reaction. The ADN is the only reactant.) The reaction releases a lot of heat, so the gases are initially formed at high temperature and pressure. The thrust of the rocket results mainly from the expansion of this gas mixture. Suppose a 2.3-kg sample of ADN is denoted and decomposes completely to give N2,O2, and H2O. If the resulting gas mixture expands until it reaches a temperature of 100°C and a pressure of 1.00 atm, what volume will it occupy? Is your answer consistent with the proposed use of ADN as a rocket fuel?arrow_forward
- When limestone (solid CaCO3) is heated, it decomposes into lime (solid CaO) and carbon dioxide gas. This is an extremely useful industrial process of great antiquity, because powdered lime mixed with water is the basis for mortar and concrete — the lime absorbs CO2 from the air and turns back into hard, durable limestone. Suppose some calcium carbonate is sealed into a limekiln of volume 550.L and heated to 700.0°C. When the amount of CaCO3 has stopped changing, it is found that 4.14kg have disappeared. Calculate the pressure equilibrium constant Kp this experiment suggests for the equilibrium between CaCO3 and CaO at 700.0°C. Round your answer to 2 significant digits. Note for advanced students: it's possible there was some error in this experiment, and the value it suggests for Kp does not match the accepted value.arrow_forwardWhen limestone (solid CaCO,) is heated, it decomposes into lime (solid CaO) and carbon dioxide gas. This is an extremely useful industrial process of great antiquity, because powdered lime mixed with water is the basis for mortar and concrete- the lime absorbs CO₂ from the air and turns back into hard, durable limestone. Suppose some calcium carbonate is sealed into a limekiln of volume 500. L. and heated to 520.0 °C. When the amount of CaCO, has stopped changing, it is found that 3.84 kg have disappeared. Calculate the pressure equilibrium constant K, this experiment suggests for the equilibrium between CaCO, and CaO at 520.0 °C. Round your answer to 2 significant digits. Note for advanced students: it's possible there was some error in this experiment, and the value it suggests for K, does not match the accepted value.arrow_forwardWhen limestone (solid CaCO3) is heated, it decomposes into lime (solid CaO) and carbon dioxide gas. This is an extremely useful industrial process of great antiquity, because powdered lime mixed with water is the basis for mortar and concrete – the lime absorbs CO, from the air and turns back into hard, durable limestone. Suppose some calcium carbonate is sealed into a limekiln of volume 850. L and heated to 520.0 °C. When the amount of CaCO, has stopped changing, it is found that 13.1 kg have disappeared. Calculate the pressure equilibrium constant K, this experiment suggests for the equilibrium between CaCO, and CaO at 520.0 °C. Round your answer to 2 significant digits. Note for advanced students: it's possible there was some error in this experiment, and the value it suggests for K, does not match the accepted value. K, - 0arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY