Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 5, Problem 49QAP
When acetylene, C2H2, is burned in oxygen, carbon dioxide and steam are formed. A sample of acetylene with a volume of 7.50 L and a pressure of 1.00 atm is burned in excess oxygen at 225°C. The products are transferred without loss to a 10.0-L. flask at the same temperature.
(a) Write a balanced equation for the reaction.
(b) What is the total pressure of the products in the 10.0-L flask?
(c) What is the partial pressure of each of the products in the flask?
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d) Determine the formal charge on the nitrogen atom in each of the structures.
NH3
NH2
N
C
бобкат
: N
N
H
H
Н
H2N-OH
A
B
C
D
E
F
G
Lewis Structure, Hybridization & Molecular Geometry
a) Draw the Lewis Structure of the molecules; Label the hybridization of each carbon atom;
Predict the approximate molecular geometry around each carbon atom.
CH3CHO
CH3CN
b) Draw the Lewis Structure of Nitromethane; Predict the approximate molecular geometry
around the nitrogen atom.
CH3NO2
c) Draw the Lewis Structure; Label the hybridization of the boron atom; Predict the
approximate molecular geometry.
BF3
BF4
Chapter 5 Solutions
Chemistry: Principles and Reactions
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Ch. 5 - Prob. 11QAPCh. 5 - A sealed tank at room temperature, 25C, has 22.0 g...Ch. 5 - A balloon filled with helium hasa volume of...Ch. 5 - Prob. 14QAPCh. 5 - Prob. 15QAPCh. 5 - Prob. 16QAPCh. 5 - A piece of dry ice (CO2(s)) has a mass of 22.50 g....Ch. 5 - A four-liter tank is filled with propane gas,...Ch. 5 - Prob. 19QAPCh. 5 - Prob. 20QAPCh. 5 - Calculate the densities (in g/L) of the following...Ch. 5 - Calculate the densities (in grams per liter) of...Ch. 5 - Helium-filled balloons rise in the air because the...Ch. 5 - Space probes to Mars have shown that its...Ch. 5 - Cyclopropane mixed in the proper ratio with oxygen...Ch. 5 - Phosgene is a highly toxic gas made up of carbon,...Ch. 5 - The gas in the discharge cell of a laser contains...Ch. 5 - Exhaled air contains 74.5% N2, 15.7% O2, 3.6% CO2,...Ch. 5 - A 1.58-g sample of C2H3X3(g) has a volume of 297...Ch. 5 - A 0.750-g sample of the gas PX3 is in a sealed...Ch. 5 - Nitrogen oxide is a pollutant commonly found in...Ch. 5 - Nitrogen trifluoride gas reacts with steam to...Ch. 5 - Dichlorine oxide is used as bactericide to purify...Ch. 5 - Titanium(III) chloride is used in the manufacture...Ch. 5 - Nitric acid can be prepared by bubbling dinitrogen...Ch. 5 - Potassium peroxide is used to absorb the CO2...Ch. 5 - Hydrogen cyanide (HCN) is a poisonous gas. It can...Ch. 5 - When hydrogen peroxide decomposes, oxygen is...Ch. 5 - Ammonium nitrate can be used as an effective...Ch. 5 - Acetone peroxide, C9H18O6(s), is a powerful but...Ch. 5 - Prob. 41QAPCh. 5 - A certain laser uses a gas mixture consisting of...Ch. 5 - A sample of a smoke stack emission was collected...Ch. 5 - Prob. 44QAPCh. 5 - Prob. 45QAPCh. 5 - Prob. 46QAPCh. 5 - Prob. 47QAPCh. 5 - Follow the instructions of Problem 47 for the...Ch. 5 - When acetylene, C2H2, is burned in oxygen, carbon...Ch. 5 - When ammonium nitrate decomposes at 722C,...Ch. 5 - Prob. 51QAPCh. 5 - Nitrogen gas can be obtained by decomposing...Ch. 5 - Prob. 53QAPCh. 5 - Prob. 54QAPCh. 5 - Prob. 55QAPCh. 5 - Prob. 56QAPCh. 5 - A gas effuses 1.55 times faster than propane...Ch. 5 - A gas effuses through an opening one-fifth as fast...Ch. 5 - Prob. 59QAPCh. 5 - Prob. 60QAPCh. 5 - At what temperature will a molecule of uranium...Ch. 5 - Calculate the average speed of a (a) chlorine...Ch. 5 - Prob. 63QAPCh. 5 - Prob. 64QAPCh. 5 - Prob. 65QAPCh. 5 - Prob. 66QAPCh. 5 - Prob. 67QAPCh. 5 - Prob. 68QAPCh. 5 - Prob. 69QAPCh. 5 - Given that 1.00 mol of neon and 1.00 mol of...Ch. 5 - An intermediate reaction used in the production of...Ch. 5 - Prob. 72QAPCh. 5 - Prob. 73QAPCh. 5 - Glycine is an amino acid made up of carbon,...Ch. 5 - Prob. 75QAPCh. 5 - The Lamborghini Aventador engine has a 12-cylinder...Ch. 5 - Prob. 77QAPCh. 5 - Prob. 78QAPCh. 5 - Prob. 79QAPCh. 5 - Prob. 80QAPCh. 5 - Prob. 81QAPCh. 5 - Prob. 82QAPCh. 5 - Prob. 83QAPCh. 5 - The graph below shows the distribution of...Ch. 5 - Consider the following sketch. Each square in bulb...Ch. 5 - The following figure shows three 1.00-L bulbs...Ch. 5 - Prob. 87QAPCh. 5 - Prob. 88QAPCh. 5 - Prob. 89QAPCh. 5 - Prob. 90QAPCh. 5 - Prob. 91QAPCh. 5 - A 0.2500-g sample of an Al-Zn alloy reacts with...Ch. 5 - Prob. 93QAPCh. 5 - A mixture in which the mole ratio of hydrogen to...
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- a. The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 " is best described as a hybrid of several contributing resonance forms, two of which are shown here. HO :0: HO + :Ö: Bicarbonate is crucial for the control of body pH (for example, blood pH 7.4). A more self-indulgent use is in baking soda, where it serves as a source of CO2 CO2 gas, which gives bread and pastry their fluffy constituency. (i) Draw at least one additional resonance form. = (ii) Using curved "electron-pushing" arrows, show how these Lewis structures may be interconverted by movement of electron pairs. (iii) Determine which form or forms will be the major contributor(s) to the real structure of bicarbonate, explaining your answer on the basis of the criteria in Section 1-5.arrow_forwardCalibri 11 + BIL NAME: Jaylena M A student is investigating the ctect of volume on pressure during a lab activity. The student uses the following volumes (mL). 12, 13, 14, 16, 17, 18, 19, 20, 21, 22, 23, 24, 26, 28, 30, 33, 34, 35, 38, 40, 42, 44. 46, and 50. As the volume changed they measured the following pressures (atm) 11.0, 10.5, 10.0, 9.2. 8.5, 78, 75, 7.0, 6.8, 6.5, 6.0, 5.9, 5.5, 5.0, 4.8, 4.5, 4.2, 3.9, 3.8, 3.5, 3.3, 3.2, 3.0, 2.9. What is the independent variable? Volume Imla What is the dependent variable? Pressure Jatm Use the data and make a PROPER data table. Volume 1mL) Pressure latm 110arrow_forwardDraw all resonance forms of the molecules. Include curved arrow notation. Label major resonance contributor.arrow_forward
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