Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 5, Problem 60QAP
Interpretation Introduction

Interpretation:

Two gases NH3 and phosphine gas, PH3 are effusing through a small pinhole at same temperature. 1.73 ×10-3 mol NH3 gas takes time of 11.2 second for effusing. Time taken by PH3 with same amount that is 1.73 ×10-3 mol is to be determined.

Concept introduction:

Rate of effusion of is a process of escaping of molecules from high pressure to lower pressure at particular rate. Itcan be calculated by dividing moles of gas by time of effusion. Given as-

rate=(nt)

Where n = moles of gas

t = effusion time

Rate of effusion is also inversely proportional to the square root of the molar mass of atom. Ratio of rate of effusion is given as-

Rate of effusion of gas ARate of effusion of gas B=(Molar mass of gas BMolar mass of gas A)1/2

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Chapter 5 Solutions

Chemistry: Principles and Reactions

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