Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 5, Problem 52QAP
Nitrogen gas can be obtained by decomposing ammonium nitrate at high temperatures. The nitrogen gas is collected over water in a 500-mL (three significant figures) flask at 19°C. The ambient pressure is 745 mm Hg. (Vapor pressure of water at 19°C is 16.48 mm Hg.)
(a) What is the partial pressure of nitrogen?
(b) How many moles of water are there in the wet gas?
(c) How many moles of dry gas are collected?
(d) If 0.128 g of Ne are added to the flask at the same temperature, what is the partial pressure of neon in the flask?
(e) What is the total pressure after Ne is added?
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Quiz 9
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Quiz #9 =
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Draw the major products of the following. Show Stereochemistry when applicable:
1. OsO4
A
2. NaHSO 3, H 20
Cl₂
➤ C
H2, Pd/C
E
HBr
1. Hg(OAc) 2, H₂O
2. NaBH 4
Ꭰ
KI, H3PO4
F
KMnO4, H3O+
KMnO4, H2O
G
H
HBr
Br2
J
CH2N2
➤
K
CH2I2, Zn(Cu)
Cl2, CH3OH
C
1. 03
2. Zn, H3O+
HCI
1. BH 3
N
M
2. NaOH, H 202
KMnO4, NaOH
H₂O
P
Br2, H2O
R
1. BH 3
2. NaOH, H 202
Cl2, CH3CH2OH T
Select the
stronger base:
H-CEN
equally basic
H
H H
H-C-N
H
Select the
stronger acid:
Select the
stronger base:
Select the
stronger base:
H
-H
equally acidic
о
equally basic
NH
equally basic
о
Classify each of the following as either a substitution, elimination, or addition reaction.
CH3
CH3
CH3-CH-CH2-C-CH3 + Br₂
CH3
CH3
CH3
CH3-C-CH2-C-CH3 + HBr
substitution
○ elimination
Br
CH3
CHI CHO CHA HO CH
он
Cl
CH3-CH2-CH-CH2-CH3
CH₂
DBU
H*
-
CHI CHO CH3 + H2O
Ӧ
CH3
CH3-CH2-CH=CH-CH3 + HCI
OH
Pd/C
CH3
CH3-CH-CH2-C-CH3
CH3
H
C-CH2-CH3 + HO-CH3
addition
substitution
elimination
○ addition
○ substitution
○ elimination
O addition
substitution
O elimination
addition
substitution
O elimination
addition
CH3
C-CH3 + H2
CH3
CH3-O-CH-CH2-CH3
Он
Chapter 5 Solutions
Chemistry: Principles and Reactions
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