Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 5, Problem 61QAP
At what temperature will a molecule of uranium hexafluoride, the densest gas known, have the same average speed as a molecule of the lightest gas, hydrogen, at 37°C?
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b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
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WHY?
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H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
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MUST INDICATE H -2
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Br
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most stable
WHY?
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12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
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HOH
OH
3
Conformer A:
Br
OH
A
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Br H
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Br
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CH₂
H
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C
D
E
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Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
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Chapter 5 Solutions
Chemistry: Principles and Reactions
Ch. 5 - Prob. 1QAPCh. 5 - A 6.00-ft cylinder has a radius of 26 in. It...Ch. 5 - Prob. 3QAPCh. 5 - Prob. 4QAPCh. 5 - A cylinder with a movable piston records a volume...Ch. 5 - A tank is filled with gas to a pressure of 875 mm...Ch. 5 - A sample of CO2 gas at 22C and 1.00 atm has a...Ch. 5 - A sample of nitrogen gas has a pressure of 1.22...Ch. 5 - Prob. 9QAPCh. 5 - A tire is inflated to a gauge pressure of 28.0 psi...
Ch. 5 - Prob. 11QAPCh. 5 - A sealed tank at room temperature, 25C, has 22.0 g...Ch. 5 - A balloon filled with helium hasa volume of...Ch. 5 - Prob. 14QAPCh. 5 - Prob. 15QAPCh. 5 - Prob. 16QAPCh. 5 - A piece of dry ice (CO2(s)) has a mass of 22.50 g....Ch. 5 - A four-liter tank is filled with propane gas,...Ch. 5 - Prob. 19QAPCh. 5 - Prob. 20QAPCh. 5 - Calculate the densities (in g/L) of the following...Ch. 5 - Calculate the densities (in grams per liter) of...Ch. 5 - Helium-filled balloons rise in the air because the...Ch. 5 - Space probes to Mars have shown that its...Ch. 5 - Cyclopropane mixed in the proper ratio with oxygen...Ch. 5 - Phosgene is a highly toxic gas made up of carbon,...Ch. 5 - The gas in the discharge cell of a laser contains...Ch. 5 - Exhaled air contains 74.5% N2, 15.7% O2, 3.6% CO2,...Ch. 5 - A 1.58-g sample of C2H3X3(g) has a volume of 297...Ch. 5 - A 0.750-g sample of the gas PX3 is in a sealed...Ch. 5 - Nitrogen oxide is a pollutant commonly found in...Ch. 5 - Nitrogen trifluoride gas reacts with steam to...Ch. 5 - Dichlorine oxide is used as bactericide to purify...Ch. 5 - Titanium(III) chloride is used in the manufacture...Ch. 5 - Nitric acid can be prepared by bubbling dinitrogen...Ch. 5 - Potassium peroxide is used to absorb the CO2...Ch. 5 - Hydrogen cyanide (HCN) is a poisonous gas. It can...Ch. 5 - When hydrogen peroxide decomposes, oxygen is...Ch. 5 - Ammonium nitrate can be used as an effective...Ch. 5 - Acetone peroxide, C9H18O6(s), is a powerful but...Ch. 5 - Prob. 41QAPCh. 5 - A certain laser uses a gas mixture consisting of...Ch. 5 - A sample of a smoke stack emission was collected...Ch. 5 - Prob. 44QAPCh. 5 - Prob. 45QAPCh. 5 - Prob. 46QAPCh. 5 - Prob. 47QAPCh. 5 - Follow the instructions of Problem 47 for the...Ch. 5 - When acetylene, C2H2, is burned in oxygen, carbon...Ch. 5 - When ammonium nitrate decomposes at 722C,...Ch. 5 - Prob. 51QAPCh. 5 - Nitrogen gas can be obtained by decomposing...Ch. 5 - Prob. 53QAPCh. 5 - Prob. 54QAPCh. 5 - Prob. 55QAPCh. 5 - Prob. 56QAPCh. 5 - A gas effuses 1.55 times faster than propane...Ch. 5 - A gas effuses through an opening one-fifth as fast...Ch. 5 - Prob. 59QAPCh. 5 - Prob. 60QAPCh. 5 - At what temperature will a molecule of uranium...Ch. 5 - Calculate the average speed of a (a) chlorine...Ch. 5 - Prob. 63QAPCh. 5 - Prob. 64QAPCh. 5 - Prob. 65QAPCh. 5 - Prob. 66QAPCh. 5 - Prob. 67QAPCh. 5 - Prob. 68QAPCh. 5 - Prob. 69QAPCh. 5 - Given that 1.00 mol of neon and 1.00 mol of...Ch. 5 - An intermediate reaction used in the production of...Ch. 5 - Prob. 72QAPCh. 5 - Prob. 73QAPCh. 5 - Glycine is an amino acid made up of carbon,...Ch. 5 - Prob. 75QAPCh. 5 - The Lamborghini Aventador engine has a 12-cylinder...Ch. 5 - Prob. 77QAPCh. 5 - Prob. 78QAPCh. 5 - Prob. 79QAPCh. 5 - Prob. 80QAPCh. 5 - Prob. 81QAPCh. 5 - Prob. 82QAPCh. 5 - Prob. 83QAPCh. 5 - The graph below shows the distribution of...Ch. 5 - Consider the following sketch. Each square in bulb...Ch. 5 - The following figure shows three 1.00-L bulbs...Ch. 5 - Prob. 87QAPCh. 5 - Prob. 88QAPCh. 5 - Prob. 89QAPCh. 5 - Prob. 90QAPCh. 5 - Prob. 91QAPCh. 5 - A 0.2500-g sample of an Al-Zn alloy reacts with...Ch. 5 - Prob. 93QAPCh. 5 - A mixture in which the mole ratio of hydrogen to...
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- The molar conductivity of a very dilute solution of NaCl has been determined. If it is diluted to one-fourth of the initial concentration, qualitatively explain how the molar conductivity of the new solution will compare with the first.arrow_forwardWhat does the phrase mean, if instead of 1 Faraday of electricity, Q coulombs (Q/F Faradays) pass through?arrow_forwardWhat characteristics should an interface that forms an electrode have?arrow_forward
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