General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 5, Problem 5.91P
What is the percent yield of B in a reaction that uses 10.0 g of starting material A, has a theoretical yield of 12.0 g of B, and an actual yield of 9.0 g of B?
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What spectral features allow you to differentiate the product from the starting material?
Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR.
2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too.
3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.
Chapter 5 Solutions
General, Organic, & Biological Chemistry
Ch. 5.1 - Use the molecular art to identify the process as a...Ch. 5.1 - Use the molecular art to identify the process as a...Ch. 5.1 - Label the reactants and products, and indicate how...Ch. 5.1 - One term in a balanced chemical equation contained...Ch. 5.2 - Write a balanced equation for each reaction....Ch. 5.2 - Write a balanced equation for the following...Ch. 5.2 - Write a balanced equation for the reaction of...Ch. 5.2 - Balance each chemical equation. Al+H2SO4Al2(...Ch. 5.3 - Write a balanced equation for the reaction...Ch. 5.3 - Classify each reaction as a combination or...
Ch. 5.3 - Classify each reaction as a single replacement or...Ch. 5.3 - Classify each reaction as a combination,...Ch. 5.3 - Fill in the needed reactants or products for each...Ch. 5.4 - Identify the species that is oxidized and the...Ch. 5.4 - Identify the species that is oxidized and the...Ch. 5.4 - Prob. 5.16PCh. 5.5 - How many items are contained in one mole of (a)...Ch. 5.5 - How many carbon atoms are contained in each of the...Ch. 5.5 - How many molecules are contained in each of the...Ch. 5.5 - How many moles of water contain each of the...Ch. 5.6 - Calculate the formula weight of each ionic...Ch. 5.6 - The unmistakable odor of a freshly cut cucumber is...Ch. 5.6 - Prob. 5.23PCh. 5.6 - Calculate the number of grams contained in each of...Ch. 5.6 - How many moles are contained in each of the...Ch. 5.6 - How many molecules are contained in two 500.-mg...Ch. 5.7 - Use the balanced equation for the reaction of N2...Ch. 5.7 - Use the balanced equation in Sample Problem 5.15...Ch. 5.8 - Prob. 5.29PCh. 5.8 - Using the balanced equation for the combustion of...Ch. 5.8 - Prob. 5.31PCh. 5.8 - Use the balanced equation, N2+O22NO, to answer the...Ch. 5.9 - Prob. 5.33PCh. 5.9 - Prob. 5.34PCh. 5.9 - The synthetic antiviral drug Tamiflu, currently...Ch. 5.10 - Consider the reaction of hydrogen and nitrogen to...Ch. 5.10 - Using the balanced equation for the reaction of H2...Ch. 5.10 - Using the balanced equation, 3H2(g)+N2(g)2NH3(g),...Ch. 5.10 - Using the balanced equation, N2(g)+O2(g)2NO(g),...Ch. 5.10 - Prob. 5.41PCh. 5.10 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - How many atoms of each element are drawn on each...Ch. 5 - How many atoms of each element are drawn on each...Ch. 5 - Use the molecular art to write a balanced equation...Ch. 5 - Prob. 5.48PCh. 5 - Balance each equation. a....Ch. 5 - Balance each equation. a....Ch. 5 - Prob. 5.51PCh. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - For the reaction depicted in the molecular art:...Ch. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - Prob. 5.58PCh. 5 - Classify the reaction depicted in the molecular...Ch. 5 - Classify the reaction depicted in the molecular...Ch. 5 - Classify each reaction as combination,...Ch. 5 - Classify each reaction as combination,...Ch. 5 - Fill in the needed reactant or product for each of...Ch. 5 - Fill in the needed reactant or product for each of...Ch. 5 - Identify the species that is oxidized and the...Ch. 5 - Identify the species that is oxidized and the...Ch. 5 - Prob. 5.67PCh. 5 - Rechargeablenickel-cadmium batteries are used in...Ch. 5 - The reaction of hydrogen (H2) with acetylene...Ch. 5 - Prob. 5.70PCh. 5 - Calculate the formula weight and molar mass of...Ch. 5 - Calculate the formula weight and molar mass of...Ch. 5 - L-Dopa is a drug used to treat Parkinson’s...Ch. 5 - Niacin, vitamin B3, is found in soybeans, which...Ch. 5 - Which quantity has the greater mass? 1 mol of Fe...Ch. 5 - Prob. 5.76PCh. 5 - Mescaline is a hallucinogen in peyote, a cactus...Ch. 5 - Prob. 5.78PCh. 5 - How many grams are contained in 5.00 mol of each...Ch. 5 - How many grams are contained in 0.50 mol of each...Ch. 5 - Prob. 5.81PCh. 5 - How many moles are contained in each number of...Ch. 5 - Prob. 5.83PCh. 5 - Prob. 5.84PCh. 5 - Prob. 5.85PCh. 5 - Prob. 5.86PCh. 5 - Using the balanced equation for the combustion of...Ch. 5 - Sodium metal (Na) reacts violently when added to...Ch. 5 - Prob. 5.89PCh. 5 - Prob. 5.90PCh. 5 - What is the percent yield of B in a reaction that...Ch. 5 - What is the percent yield of B in a reaction that...Ch. 5 - The reaction of methane (CH4) with Cl2forms...Ch. 5 - Methanol (CH4O), which is used as a fuel in...Ch. 5 - Consider the given reaction mixture that contains...Ch. 5 - Consider the reaction of A2 and B2 to form A2B,...Ch. 5 - Prob. 5.97PCh. 5 - Prob. 5.98PCh. 5 - Prob. 5.99PCh. 5 - Prob. 5.100PCh. 5 - The local anesthetic ethyl chloride ( C2H5Cl,...Ch. 5 - The solvent dichloromethane (, molar mass 84.93...Ch. 5 - Answer the following questions about the...Ch. 5 - Answer the following questions about diethyl ether...Ch. 5 - Prob. 5.105PCh. 5 - Prob. 5.106PCh. 5 - Prob. 5.107PCh. 5 - Prob. 5.108PCh. 5 - Prob. 5.109PCh. 5 - Prob. 5.110PCh. 5 - DDT, a pesticide that kills disease-carrying...Ch. 5 - Prob. 5.112PCh. 5 - TCDD, also called dioxin...Ch. 5 - Prob. 5.114CP
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